Product: [Cu-(bpy)(BF4)2(H2O)2](bpy)
Synonyms: Cu-bpy
CAS:854623-98-6
Basic Information
| Unit MF. |
C20H20CuN4O2.2BF4 |
Unit MW. |
585.55 |
| Coordination Metal |
Cu |
Linkers |
4,4'-bipyridine (CAS: 102-47-2)
Tetrafluoroborate (BF4^-)
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| Pore Size |
/ |
Pore Volume |
/ |
| Surface Area |
/ |
| Analog Structure |
/ |
Product Property
| Appearance |
/ |
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| Particle Size |
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Stability
1) Solution stability: NA
2) Thermal stability: NA
3) Thermal decomposition temperature: NA
Preservation
1) Keep in dry and cool condition
2) Activation by heating in a vacuum oven at room temperature for 3 hours is recommended
Other Features
Fluorescence: NA
Applications
1) Used for catalytic oxidation reactions, such as converting silyl enolates to α-hydroxy carbonyl compounds
2) Facilitates catalyst recovery and reuse through magnetic separation
Characterizations
References
1) Arai, Takayoshi; Sato, Toru; Kanoh, Hirofumi; Kaneko, Katsumi; Oguma, Koichi; Yanagisawa, Akira; Chemistry - A European Journal (2008), 14(3), 882-885, DOI: 10.1002/chem.200701371, "Organic–Inorganic Hybrid Polymer-Encapsulated Magnetic Nanobead Catalysts";
2)Francisco J. Sotomayor, Christian M. Lastoskie; Langmuir, 2017, 33, 11670-11678; DOI:10.1021/acs.langmuir.7b02036; Predicting the Breakthrough Performance of “Gating” Adsorbents Using Osmotic Framework-Adsorbed Solution Theory;