MOF-177
MOF-177
CAS:676593-65-0
M.F.:C54H30O13Zn4
M.W.:1148.37
Pricing
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Product: MOF-177
Synonyms: Basolite Z377
CAS：676593-65-0
Basic Information
| Unit MF. | C54H30O13Zn4 | Unit MW. | 1148.37 | ||
| Coordination Metal | Zn | Linkers | H3BTB（CAS：50446-44-1） | ||
| Aperture | 1.7 nm | Pore volume | 1.6 g/cm3 | ||
| Surface Area | BET surface area >3000 m2/g; | ||||
| Analog Structure |   |
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Product Property
| Appearance | Off-White / Grey Powder | |||
| Particle Size | millimeter sheet particles | |||
Stability
1) MOF-177 could be stable in sealed condition for weeks, but will gradually decompose in wet air or solution。
2) Thermally decomposition temperature above 400℃
2) Thermally decomposition temperature above 400℃
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 120 ℃ in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Efficient asorbent for methane and hydrogen
2) Efficient asorbent for methane and hydrogen
Characterizations
References
1) H. Furukawa, M. A. Miller, O. M. Yaghi, J. Mater. Chem. 2007, 17, 3197, DOI: 10.1039/B703608F ; Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal–organic frameworks
2) H. Furukawa, N. Ko, Y. B. Go, N. Aratani, S. B. Choi, E. Choi, A. Ö. Yazaydin, R. Q. Snurr, M. O’Keeffe,
J. Kim, O. M. Yaghi, science 2010, 329, 424-428, DOI: 10.1126/science.1192160 ; Ultrahigh Porosity in Metal-Organic Frameworks
3) D. J. Tranchemontagne, J. R. Hunt, O. M. Yaghi, Tetrahedron 2008, 8553–8557, doi: 10.1016/j.tet.2008.06.036 ; Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0；
4）Andrew R. Millward, Omar M. Yaghi; Journal of the American Chemical Society, 2005, 127, 51; DOI：10.1021/ja0570032; Metal-Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature；
5) David Britt, David Tranchemontagne, Omar M. Yaghi; PNAS, 2008, 105, 33; DOI：10.1073/pnas.0804900105; Metal-organic frameworks with high capacity and selectivity for harmful gases;