benzene-1,3,5- triyltris(methylene))triphosphonic acid

Product Name：1,3,5-Benzenetris(phosphonic acid)
Synonymous：H6btmp ; H6bmt;P,P',P''-[1,3,5-Benzenetriyltris(methylene)]tris[phosphonic acid]; (Benzene-1,3,5-triyltris(methylene))triphosphonic acid; Mesitylenetriphosphonic acid
CAS：586372-53-4

Basic Info

M.F.	C9H15O9P3		M.W.	360.1314
Appearance

Properties

1) It is soluble in DMF and DMSO
2) Sealed at room temperature

Appications

1) It could be used as monomer linker for MOF synthesis：Cu3(btmp)(H2O) [r2]

Characterization

HNMR

FTIR

HPLC

Reference

1) Jaffres, P.; Villemin, D.; Montouillout, V.; Fernandez, C.; Chardon, J.; Sopkova-De Oliveira Santos, J.; Molecular Crystals and Liquid Crystals Science and Technology, A 2002, 389, 87-95, Self-association of benzene-1,3,5-tris-(methylenephosphonic acid): evidence of charge-assisted hydrogen bonds

2) Yang, C.; Song, Y.; Yeh, Y.; Liu, Y.; Tseng, T.; Lu, K.; CrystEngComm 2011, 13(7), 2678-2686, DOI: 10.1039/c0ce00439a ; A flexible tris-phosphonate for the design of copper and cobalt coordination polymers: unusual cage array topology and magnetic properties

3) Tang, S.; Pan, X.; Lv, X.; Yan, S.; Xu, X.; Li, L.; Zhao, X.; CrystEngCom 2013, 15(10), 1860-1873, DOI: 10.1039/c2ce26828k ; Fabrication of new metal phosphonates from tritopic trisphosphonic acid containing methyl groups and auxiliary ligands: syntheses, structures and gas adsorption properties

4) Vilela, S.; Firmino, A.; Mendes, R.; Fernandes, J.; Ananias, D.; Valente, A.; Ott, H.; Carlos, L.; Rocha, J.; Tome, J.; Almeida Paz, F.; Chem. Commun. 2013, 49(57), 6400-6402, DOI: 10.1039/c3cc42632g ; Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties