ZIF-67
ZIF-67
CAS:46201-07-4
M.F.:C8H12N4.Co
M.W.:223.14
Pricing
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Product: ZIF-67(Co)
Synonyms: 2-Methylimidazole Cobalt salt
CAS：46201-07-4
Basic Information
| Unit MF. | C4H6N2.Co | Unit MW. | 223.14 | ||
| Coordination Metal | K | Linkers | 2-Methylimidazole（CAS：693-98-1） | ||
| Aperture | 0.34nm; 1.1nm | Pore volume | 0.66 cm3/g | ||
| Surface Area | BET Specific surface 1500 m2/g, | ||||
| Analog Structure |    |
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Product Property
| Appearance | Purple Powder |  |
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| Particle Size | 500nm-1um | |||
Stability
1) ZIF-67 is stable in air, but instable in aqueous solutions
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 5 hours at 120 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Good drug carrier, which is able to decompose in stomach and release the drug content
2) Good drug carrier, which is able to decompose in stomach and release the drug content
Characterizations
References
1) H. Wu, X. Qian, H. Zhu, S. Ma, G. Zhu, Y. Long, RSC Adv. 2016, 6, 6915-6920, DOI: 10.1039/C5RA18557B ; Controlled synthesis of highly stable zeolitic imidazolate framework-67 dodecahedra and their use towards the templated formation of a hollow Co3O4 catalyst for CO oxidation；
2）Authors: Rahul R. Salunkhe, Jing Tang, Yuichiro Kamachi, Teruyuki Nakato, Jung Ho Kim, Yusuke Yamauchi; Publication information: ACS Nano, 2015, 9, 6;DOI: 10.1021/acsnano.5b01790; Asymmetric Supercapacitors Using 3D Nanoporous Carbon and Cobalt Oxide Electrodes Synthesized from a Single Metal-Organic Framework；
3）Lu Wang, Xiao Feng, Lantian Ren, Qiuhan Piao, Jieqiang Zhong, Yuanbo Wang, Haiwei Li, Yifa Chen, Bo Wang；Journal of the American Chemical Society, 2015, 137, 14；DOI 10.1021/jacs.5b01613；Flexible Solid-State Supercapacitor Based on a Metal−Organic Framework Interwoven by Electrochemically-Deposited PANI；
4) Daniel Saliba, Manal Ammar, Moustafa Rammal, Mazen Al-Ghoul, Mohamad Hmadeh;Journal of the American Chemical Society, 2018, 140, 5;DOI: 10.1021/jacs.7b11589;Crystal Growth of ZIF-8, ZIF-67, and Their Mixed-Metal Derivatives；
5) Yinyun Lu, Wenwen Zhan, Yue He, Yiting Wang, Xiangjian Kong, Qin Kuang, Zhaoxiong Xie, Lansun Zheng;ACS Applied Materials & Interfaces, 2014, 6, 4186-4195; DOI：10.1021/am405858v; MOF-Templated Synthesis of Porous Co₃O₄ Concave Nanocubes with High Specific Surface Area and Their Gas Sensing Properties；
6) Yinyun Lu, Yiting Wang, Hongli Li, Yuan Lin, Zhiyuan Jiang, Zhaoxiong Xie, Qin Kuang, Lansun Zheng;ACS Applied Materials & Interfaces, 2015, 7, 13604-13611; DOI：10.1021/acsami.5b03177;MOF-Derived Porous Co/C Nanocomposites with Excellent Electromagnetic Wave Absorption Properties;