Product: TpTFMB
Synonyms: TpTFMB COF
CAS:2890829-59-9
Basic Information
Unit MF. |
C14H10N2F6.C9H6O6 |
Unit MW. |
530.37334 |
Coordination Metal |
None |
Linkers |
2,2'-bis(trifluoromethyl)benzidine (TFMB)
1,3,5-triformylphloroglucinol (Tp)
|
Pore Size |
~15.5 Å |
Pore volume |
0.555 cm³/g |
Surface Area |
90 m²/g |
Analog Structure |
 |
Product Property
Appearance |
Yellow powders |
 |
Particle Size |
#N/a |
Stability
1) Stable in ethanol, methanol, tetrahydrofuran, water, and acetonitrile.
2) Thermal decomposition temperature is greater than 400℃.
Preservation
1) Keep in dry and cool conditions.
2) It is recommended to activate by heating in a vacuum oven at room temperature for 3 hours before use.
Other Features
Fluorescence: NA
Applications
1) Efficient separation of isomers, such as ethylbenzene and xylene, chlorotoluene, butylbenzene, and ethyl butanoate.
2) Used as a stationary phase in gas chromatography for the separation of various isomers.
Characterizations
References
1) Tian-Tian Ma, Cheng Yang, Hai-Long Qian, Piming Ma, Tianxi Liu, Xiu-Ping Yan; ACS Applied Materials & Interfaces (2023), 15, 32926−32934, DOI: 10.1021/acsami.3c05369 ; Trifluoromethyl-Functionalized 2D Covalent Organic Framework for High-Resolution Separation of Isomers