PCN-128
PCN-128
CAS:2230488-02-3
M.F.:C108H76O30Zr6
M.W.:2401.08
Pricing
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Product: PCN-128(Zr)
Synonyms: PCN-128(Zr)-W
CAS：2230488-02-3
Basic Information
| Unit MF. | C108 H76 O30 Zr6 | Unit MW. | 1639.87 | ||
| Coordination Metal | Zr | Linkers | H4ETTC (CAS：1610858-96-2) | ||
| Pore Size | 3.8/3.5nm 1.5nm | Pore volume | 1.5 cm3/g | ||
| Surface Area | BET Specific surface 2000 m2/g, | ||||
| Analog Structure |    |
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Product Property
| Appearance |
PCN-128 form CHEMSOON is actually a mixture of two reversible forms (W/Y): PCN-128-W: White Powder; PCN-128-Y: Yellowish Powder |
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| Particle Size | ||||
Stability
1) PCN-128 is stable in air, stable in aqueous and acidic conditions(stable in PH 2-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 120 degree in vacuum.
2) It is recommended to activate for 3 hours at 120 degree in vacuum.
Other Features
Fluorescence: PCN-128W λem=470nm; PCN-128Y λem=538nm (both at λex=365nm UV)
Applications
1) Gas and pollutant adsorption
2) PCN-128 has rigid and ultralarge 1D pore channel , which is potential for adsoption/ delivery of drug molecular and fixation of peptides and enzymes.
2) PCN-128 has rigid and ultralarge 1D pore channel , which is potential for adsoption/ delivery of drug molecular and fixation of peptides and enzymes.
Characterizations
References
1) Zhang, Q.; Su, J.; Feng, D.; Wei, Z.; Zou, X.; Zhou, H.-C.; J. Am. Chem. Soc. 2015, 137, 10064-10067, DOI:10.1021/jacs.5b04695 ; Piezofluorochromic Metal–Organic Framework: A Microscissor Lift
2) Wei, Z.; Gu, Z.-Y.; Arvapally, R. K.; Chen, Y.-P.; McDougald, R. N., Jr.; Ivy, J. F.; Yakovenko, A. A.; Feng, D.; Omary, M. A.; Zhou, H.-C. J. Am. Chem. Soc. 2014, 136, 8269-8276, DOI:10.1021/ja5006866 ; Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
3) Li, P.; Moon, S.; Guelta, M.; Harvey, S.; Hupp, J.; Farha, O.; J. Am. Chem. Soc. 2016, 138(26), 8052-8055, DOI:10.1021/jacs.6b03673 ; Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability