Benzaldehyde, 4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, polymer with benzene-1,4-diamine
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Product: Por-COF
Synonyms: Benzaldehyde, 4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-, polymer with benzene-1,4-diamine
CAS：NA
Basic Information
| Unit MF. | C48H30N4O4.C6H8N2 | Unit MW. | 834.92 | ||
| Coordination Metal | None | Linkers |
5,10,15,20-tetrakis(4-benzaldehyde)porphyrin (p-Por-CHO)； |
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| Pore Size | ~1.91 nm | Pore Volume | Not mentioned | ||
| Surface Area | 714 m2/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Purple Solid | |||
| Particle Size | Irregular bulk particles | |||
Stability
1) Por-COF is unstable in high concentration benzylamine solution, its imine bonds will be destroyed by benzylamine.
Preservation
1) Keep in dry and cool condition.
2) Activate by heating in a vacuum oven at room temperature for 3 hours before use.
Other Features
NA
Applications
1) Photocatalytic selective oxidation of amines.
2) Cooperative photocatalysis with TEMPO.
Characterizations
References
1) Ji-Long Shi, Rufan Chen, Huimin Hao, Cheng Wang, and Xianjun Lang*; Angew. Chem. Int. Ed. 2020, 59, 9088–9093, DOI: 10.1002/anie.202000723 ; 2D sp2 Carbon-Conjugated Porphyrin Covalent Organic Framework for Cooperative Photocatalysis with TEMPO