MIL-160(Al)
MIL-160(Al)
CAS:2050043-43-9
M.F.:
M.W.:
Pricing
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Product: MIL-160(Al)
Synonyms: NA
CAS：2050043-43-9
Basic Information
| Unit M.F. | C6H3O6Al | Unit M.W. |
198.07 |
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| Coordination Metal | Al 3+ | Linkers |
2,5-Furandicarboxylic acid (2,5-FDCA) |
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| Pore Size | 0.4-0.6nm (0.47nm) | Pore volume | 0.40 - 0.56 cm 3 /g | ||
| Surface Area | ~1000 m 2 /g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | White solid | |||
| Particle Size | irregular clusters | |||
Stability
1) Stable in acqueos solution.
2) Thermal decomposition temperature above 300°C.
2) Thermal decomposition temperature above 300°C.
Preservation
1) Store in a dry and sealed condition at room temperature.
2) Degas at 120°C for 6 hours under vacuum before gas adsorption test.
Other Features
1) Highly hydrophilic, capable of adsorbing water vapor, with up to 4 water molecules adsorbed per unit of MOF.
2) The kinetics of water adsorption follows the pseudo-first order rate law at low adsorption amounts, with a rate constant k=0.01767min −1 .
2) The kinetics of water adsorption follows the pseudo-first order rate law at low adsorption amounts, with a rate constant k=0.01767min −1 .
Applications
1) Used in water harvesting and heat transformation for heat storage and reallocation based on water adsorption.
2) Applicable to adsorption studies, such as the adsorption of gaseous water and nitrogen.
2) Applicable to adsorption studies, such as the adsorption of gaseous water and nitrogen.
Characterizations
References
1) Tannert, N.; Jansen, C.; Nießing, S.; Janiak, C.; Dalton Transactions, 2019, 48(2967), DOI: 10.1039/c8dt04688c, Robust synthesis routes and porosity of the Al-based metal–organic frameworks Al-fumarate, CAU-10-H and MIL-160
2) Henry, B.; Samokhvalov, A.; Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2022, 267(120550), DOI: 10.1016/j.saa.2021.120550, Hygroscopic metal-organic framework MIL-160(Al): In-situ time-dependent ATR-FTIR and gravimetric study of mechanism and kinetics of water vapor sorption
3) Silva, M. P.; Ribeiro, A. M.; Silva, C. G.; Nogueira, I. B. R.; Cho, K. -H.; Lee, U. -H.; Faria, J. L.; Loureiro, J. L.; Chang, J. -S.; Rodrigues, A. E.; Ferreira, A.; Adsorption, 2021, 27(213), DOI: 10.1007/s10450-020-00286-5, MIL‑160(Al) MOF’s potential in adsorptive water harvesting;
4) Philipp Brandt, Alexander Nuhnen, Marcus Lange, Jens Mollmer, Oliver Weingart, Christoph Janiak*;ACS Applied Materials & Interfaces, 2019, 11, 17350-17358; DOI：10.1021/acsami.9b00029; Metal−Organic Frameworks with Potential Application for SO₂ Separation and Flue Gas Desulfurization；
5) Mingyu Gu, Radhakrishnan Anbarasan, Ho-Jun Cho, Jinhyuk Choi, Cheongwon Bae, Duckjong Kim, Sang Yong Nam, Seth M. Cohen, Jae Hyun Park, Juyeong Kim; J. Am. Chem. Soc. 2026, 148, 3, 3442–3454; DOI：10.1021/jacs.5c18786; Hydrophobic Metal−Organic Frameworks Enable Superior High-Pressure Ammonia Storage through Geometric Design;