MOF-303(Al)
MOF-303(Al)
CAS:2050043-41-7
M.F.:C5H2N2O5Al
M.W.:197.06
Pricing
//
Product: MOF-303(Al)
Synonyms: Al(OH)(HPDC)
CAS：2050043-41-7
Basic Information
| Unit MF. | C5H2N2O5Al | Unit MW. | 197.06128 | ||
| Coordination Metal | Al | Linkers |
1H-pyrazole-3,5-dicarboxylic acid（H2PDC, CAS：3112-31-0） |
||
| Aperture | pore channels 0.6 nm | Pore volume | 0.54 cm3/g | ||
| Surface Area | BET Specific surface 800-1100 m2/g | ||||
| Analog Structure |   |
||||
Product Property
| Appearance | White Powder |  |
||
| Particle Size | 500nm-1um flake particles | |||
Stability
1) MOF-303(Al) is stable in air, stable in aqueous and week alkaline solutions; instable in strong base solutions
2) High thermal stability, thermal decomposition temperature above 400 ° C
2) High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas and pollutions (e.g. metals ions) adsorption
2) Lewis acid catalyst
2) Lewis acid catalyst
3) MOF-303 could adsorb moisutre at low humidity (0.23g H2O/g MOF-303，RH=20%), it could be applied as efficient water asorbent and industrial desiccant
Characterizations
References
1) Farhad Fathieh, Markus J. Kalmutzki, Eugene A. Kapustin, Peter J. Waller, ingjing Yang, Omar M. Yaghi, Sci. Adv. 2018, 4(6), eaat3198, DOI: 10.1126/sciadv.aat3198 ; Practical water production from desert air
2) Baosheng Liu, Lei Pei, Xudong Zhao, Xuezhi Zhang, Hongliang Huang, Chem. Eng. J., 2021, 128431, DOI: 10.1016/j.cej.2021.128431 ; Synergistic dual-pyrazol sites of metal-organic framework for efficient separation and recovery of transition metals from wastewater;
3) Nikita Hanikel, Mathieu S. Prévot, Farhad Fathieh, Eugene A. Kapustin, Hao Lyu, Haoze Wang, Nicolas J. Diercks, T. Grant Glover, Omar M. Yaghi; ACS Central Science, 2019, 5, 1699-1706; DOI：10.1021/acscentsci.9b00745; Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester ;
4）4）Zhiling Zheng, Ha L. Nguyen, Nikita Hanikel, Kelvin Kam-Yun Li, Zihui Zhou, Tianqiong Ma, Omar M. Yaghi; NATURE PROTOCOLS, 2023, 18, 136-156; DOI：10.1038/s41596-022-00756-w; High-yield, green and scalable methods for producing MOF-303 for water harvesting from desert air；
5）Woochul Song, Zhiling Zheng, Ali H. Alawadhi, Omar M. Yaghi; Nature Water, 2023, Volume 1, 626-634; DOI：10.1038/s44221-023-00103-7; MOF water harvester produces water from Death Valley desert air in ambient sunlight；
6）Zhiling Zheng, Nikita Hanikel,# Hao Lyu, and Omar M. Yaghi*;J. Am. Chem. Soc., 2022, 144, 22669−22675; DOI：10.1021/jacs.2c09756; Broadly Tunable Atmospheric Water Harvesting in Multivariate Metal−Organic Frameworks；
7）Nikita Hanikel, Daria Kurandina, Saumil Chheda, Zhiling Zheng, Zichao Rong, S. Ephraim Neumann, Joachim Sauer, J. Ilja Siepmann, Laura Gagliardi, Omar M. Yaghi; ACS Central Science, 2023, 9, 551-557; DOI：10.1021/acscentsci.3c00018; MOF Linker Extension Strategy for Enhanced Atmospheric Water Harvesting；
8）Nikita Hanikel, Xiaokun Pei, Saumil Chheda, Hao Lyu, WooSeok Jeong, Joachim Sauer, Laura Gagliardi, Omar M. Yaghi; Science, 2021, 374, 454-459; DOI：10.1126/science.abj0890; Evolution of water structures in metal-organic frameworks for improved atmospheric water harvesting