CAU-23(Al)
CAU-23(Al)
CAS:2050042-88-9
M.F.:
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Product: CAU-23(Al)
Synonyms: Al-MIL-53-TDC
CAS：654061-20-8
Basic Information
| Unit MF. | C6H3AlO5S | Unit MW. | 214.13 | ||
| Coordination Metal | Al | Linkers |
2,5-thiophenedicarboxylic acid CAS：3588-17-8 |
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| Aperture | pore channels 0.8nm*0.8nm | Pore volume | 0.7 cm3/g | ||
| Surface Area | |||||
| Analog Structure | |||||
Product Property
| Appearance | Yellow Powder | |||
| Particle Size | ||||
Stability
1) CAU-23(Al) is stable in air, stable in aqueous and alkaline solutions （PH>2）
2）High thermal stability, thermal decomposition temperature above 300 ° C
2）High thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2）CAU-23 could be used as moisture harvesting materials
2）CAU-23 could be used as moisture harvesting materials
Characterizations
References
1）Word Patent: WO2016186454
2）Wahiduzzaman, Mohammad; Reimer, Nele; Itie, Jean-Paul; Stock, Norbert; Maurin, Guillaume; Yot, Pascal G. Polyhedron 2018, 155, 144-148, DOI: 10.1016/j.poly.2018.08.045 ; Mechanical-pressure induced response of the MOF Al-MIL-53-TDC
3）Lopez-Olvera, Alfredo; Zarate, J. Antonio; Martinez-Ahumada, Eva; Fan, Dong ; Diaz-Ramirez, Mariana L.; Saenz-Cavazos, Paola A.; Martis, Vladimir; Williams, Daryl R. ; Sanchez-Gonzalez, Eli; Maurin, Guillaume; Ibarra, Ilich A.; ACS Applied Materials & Interfaces 2021, 13(33), 39363-39370, DOI: 10.1021/acsami.1c09944 ; SO2 Capture by Two Aluminum-Based MOFs: Rigid-like MIL-53(Al)-TDC versus Breathing MIL-53(Al)-BDC
4）Zheng, Zhiling ; Hanikel, Nikita ; Lyu, Hao ; Yaghi, Omar M.; Journal of the American Chemical Society 2022, 144(49), 22669-22675, DOI: 10.1021/jacs.2c09756 ; Broadly Tunable Atmospheric Water Harvesting in Multivariate Metal-Organic Frameworks
5) Dirk Lenzen, Jingjing Zhao, Sebastian-Johannes Ernst, Mohammad Wahiduzzaman, A. Ken Inge, Dominik Fröhlich, Hongyi Xu, Hans-Jörg Bart, Christoph Janiak, Stefan Henninger, Guillaume Maurin, Xiaodong Zou & Norbert Stock, Nature Communications 2019, 10, 3025, DOI: 10.1038/s41467-019-10960-0 ; A metal–organic framework for efficient water-based ultra-low-temperature-driven cooling ;
6) Mingyu Gu, Radhakrishnan Anbarasan, Ho-Jun Cho, Jinhyuk Choi, Cheongwon Bae, Duckjong Kim, Sang Yong Nam, Seth M. Cohen, Jae Hyun Park, Juyeong Kim; J. Am. Chem. Soc. 2026, 148, 3, 3442–3454; DOI：10.1021/jacs.5c18786; Hydrophobic Metal−Organic Frameworks Enable Superior High-Pressure Ammonia Storage through Geometric Design;