Cobalt, [[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzenaminato]](2-)]-, (SP-4-1)-, polymer with [1,1′-biphenyl]-4,4′-dicarboxaldehyde
Cobalt, [[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzenaminato]](2-)]-, (SP-4-1)-, polymer with [1,1′-biphenyl]-4,4′-dicarboxaldehyde
CAS:1809402-50-3
M.F.:C44H32CoN8.C14H10O2
M.W.:941.94
Pricing
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Product: COF-367-Co
Synonyms: Cobalt, [[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl-κN21,κN22,κN23,κN24)tetrakis[benzenaminato]](2-)]-, (SP-4-1)-, polymer with [1,1′-biphenyl]-4,4′-dicarboxaldehyde
CAS：1809402-50-3
Basic Information
| Unit MF. | C44H32CoN8.C14H10O2 | Unit MW. | 941.94 | ||
| Coordination Metal | Co | Linkers |
1) [1,1'-Biphenyl]-4,4'-dicarbaldehyde(CAS:66-98-8) 2) 5,10,15,20-tetrakis-(4-aminophenyl)-porphyrin-co-(ii)(CAS:67201-98-3) |
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| Pore Size | ~25 Å | Pore Volume | 0.2 cm³/g | ||
| Surface Area | 442 m²/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Purple powders with rectangular rod-shaped morphology | |||
| Particle Size | Approximately 100 nm | |||
Stability
1) Stable in water and ethanol
2) Thermal decomposition temperature > 300°C
2) Thermal decomposition temperature > 300°C
Preservation
1) Keep in dry and cool condition
2) It is recommended to activate the sample by heating at room temperature in a vacuum oven for 3 hours before use.
Other Features
Fluorescence: Not mentioned
Applications
1) Efficient photocatalytic CO2 reduction to CO with high selectivity and activity under visible light.
2) Suitable for visible-light-driven photocatalytic reactions.
Characterizations
References
1) Gong, Yun-Nan; Zhong, Wenhui; Li, Yang; Qiu, Yunze; Zheng, Lirong; Jiang, Jun; Jiang, Hai-Long; J. Am. Chem. Soc. 2020, 142, 16723−16731, DOI: 10.1021/jacs.0c07206; Regulating Photocatalysis by Spin-State Manipulation of Cobalt in Covalent Organic Frameworks
2) Liu, Wenbo; Li, Xiaokang; Wang, Chiming; Pan, Houhe; Liu, Wenping; Wang, Kang; Zeng, Qingdao; Wang, Rongming; Jiang, Jianzhuang; J. Am. Chem. Soc. 2019, 141, 17431−17440, DOI: 10.1021/jacs.9b09502; A Scalable General Synthetic Approach toward Ultrathin Imine-Linked Two-Dimensional Covalent Organic Framework Nanosheets for Photocatalytic CO2 Reduction