NH2-MIL-101(Cr)
NH2-MIL-101(Cr)
CAS:1414869-95-6
M.F.:C24H19Cr3FN3O15
M.W.:764.40
Pricing
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Product: NH2-MIL-101(Cr)
Synonyms: NA
CAS：1414869-95-6
Basic Information
| Unit MF. | C24N3O15FCr3 | Unit MW. | 745.2546 | ||
| Coordination Metal | Cr | Linkers | 2-Amino-Terephthalic acid (CAS:10312-55-7） | ||
| Aperture |
Aperture:1.2-1.6nm; Pore Size: 2.9-3.4nm |
Pore volume | ~2.0 cm3/g | ||
| Surface Area | BET Specific surface 2000 m2/g, | ||||
| Analog Structure |  |
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Product Property
| Appearance | Grey Green Powder |  |
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| Particle Size | 100-200nm; 500-800nm | |||
Stability
1) NH2-MIL-101(Cr) is stable in air and acqeous solutions (PH 1-12)
2）Thermal stability, thermal decomposition temperature above 300 ° C
2）Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
Characterizations
References
1) D. Jiang, L. Keenan, A. Burrows, K. Edler, Chem. Commun., 2012,48, 12053-12055, DOI: 10.1039/C2CC36344E
2) K. Li, J. Yang, J. Gu, Chem. Sci., 2019, 10, 5743–5748, DOI: 10.1039/c9sc01447k；
3) Stephan Bernt, Vincent Guillerm, Christian Serre, Norbert Stock; ChemComm, 2011, 47, 2838–2840;DOI：10.1039/c0cc04526h; Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid;
4) Yi Luan, Yue Qi, Hongyi Gao, Radoelizo S. Andriamitantsoa, Nannan Zheng, Ge Wang; Journal of Materials Chemistry A, 2015, 3, 17320–17331; DOI：10.1039/c5ta00816f; A general post-synthetic modification approach of amino-tagged metal–organic frameworks to access efficient catalysts for the Knoevenagel condensation reaction;
5) Anupam Khutia, Holger Urs Rammelberg, Thomas Schmidt, Stefan Henninger, Christoph Janiak; Chemistry of Materials, 2013, 25, 790−798; DOI：10.1021/cm304055k; Water Sorption Cycle Measurements on Functionalized MIL-101Cr for Heat Transformation Application;
6) Yu-Ri Lee, Kwangsun Yu, Seenu Ravi, Wha-Seung Ahn; ACS Applied Materials & Interfaces, 2018, 10, 23918−23927; DOI：10.1021/acsami.8b07130; Selective Adsorption of Rare Earth Elements over Functionalized Cr-MIL-101;
7) Dongmei Jiang, Luke L. Keenan, Andrew D. Burrows, Karen J. Edler; Chemical Communications, 2012, 48, 99; DOI：10.1039/c2cc36344e; Synthesis and post-synthetic modification of MIL-101(Cr)-NH₂ via a tandem diazotisation process;