Product: TpPa-COF-(CH3)2
Synonyms: 1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 2,5-dimethyl-1,4-benzenediamine
CAS: 1414350-38-1
Basic Information
| Unit MF. | 
C9H6O6.C8H12N2 | 
Unit MW. | 
346.33462 | 
| Coordination Metal | 
None | 
Linkers | 
 1,3,5-triformylphloroglucinol (Tp) 2,5-dimethylbenzene-1,4-diamine (Pa-(CH3)2)  
 | 
| Pore Size | 
~1.27 nm | 
Pore Volume | 
0.68 cm³/g | 
| Surface Area | 
124.3 m²/g | 
| Analog Structure | 
/ | 
Product Property
| Appearance | 
Red Powders | 
  | 
| Particle Size | 
Irregular bulk particles | 
Stability
1) Stable in water and ethanol
2) Thermal decomposition temperature > 300°C
Preservation
1) Store in a dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use
 
Other Features
Fluorescence: NA
Applications
1) Photocatalytic hydrogen production
2) Gas adsorption and separation
Characterizations
References
1) Jin Zhang, Cheng Cheng, Lijiang Guan, Hai-Long Jiang, Shangbin Jin; J. Am. Chem. Soc. 2023, 145, 21974−21982, DOI: 10.1021/jacs.3c06764; Rapid Synthesis of Covalent Organic Frameworks with a Controlled Morphology: An Emulsion Polymerization Approach via the Phase Transfer Catalysis Mechanism