PCN-222(Cu)
PCN-222(Cu)
CAS:1403461-04-0
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Product: PCN-222(Cu)
Synonyms: [5,10,15,20-Tetrakis(4-carboxyphenyl)porphyrinato]-Cu(II)
CAS：1403461-04-0
Basic Information
| Unit MF. | C96H48N8O32Cu2Zr6 | Unit MW. | |||
| Coordination Metal | Cu | Linkers |
5,10,15,20-Tetrakis(4-carboxyphenyl)porphyrin (TCPP) |
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| Pore Size | ~3.2 nm | Pore Volume | 1.39 cm3/g | ||
| Surface Area | 2312 m2/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Dark Red Solid | |||
| Particle Size | ||||
Stability
1) Stable in water, boiling water, and various concentrations of HCl (2M, 4M, 8M, and concentrated HCl) for 24 hours.
2) Thermal decomposition temperature is around 400℃.
2) Thermal decomposition temperature is around 400℃.
Preservation
1) Store in a dry and cool condition.
2) Activate by heating at room temperature under vacuum for 3 hours.
Other Features
Fluorescence: NA
Applications
1) Acts as a biomimetic catalyst for oxidation reactions of various substrates.
2) Exhibits high stability and catalytic activity in extreme conditions.
2) Exhibits high stability and catalytic activity in extreme conditions.
Characterizations
References
1) Dawei Feng, Zhi-Yuan Gu, Jian-Rong Li, Hai-Long Jiang, Zhangwen Wei, and Hong-Cai Zhou; Angewandte Chemie International Edition 2012, 51, 10307–10310; DOI: 10.1002/anie.201204475; Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts