UIO-66-COOH
UIO-66-COOH
CAS:1334722-04-1
M.F.:C54H22O44Zr6.H6
M.W.:1928.12
Pricing
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Product: UIO-66-COOH
Synonyms: NA
CAS：1334722-04-1
Basic Information
| Unit MF. | C54H18O44Zr6-6.H+ | Unit MW. | 1918.90 | ||
| Coordination Metal | Zr | Linkers | Trimellitic acid (CAS: 528-44-9) | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | |||
| Surface Area | BET Specific surface 600-700 m2/g, | ||||
| Analog Structure | |||||
Product Property
| Appearance | Off-White Powder | |||
| Particle Size | 200-800nm | |||
Stability
1) UIO-66-COOH is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 350 ° C
2）High thermal stability, thermal decomposition temperature above 350 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
2) It is recommended to activate for 3-5 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) UIO-66-COOH has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
2) UIO-66-COOH has branch carboxylic groups, which could be used to bind with peptide or enzyme. The carboxylic groups might also be coordinated with metal ions, used as metal probes.
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs
3) Y. Khabzina, J. Dhainaut, M. Ahlhelm, H.-J. Richter, H. Reinsch, N. Stock, D. Farrusseng, Ind. Eng. Chem. Res. 2018, 57, 24, 8200-8208, DOI: 10.1021/acs.iecr.8b00808 ; Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters；
4）Qingyuan Yang, Andrew D. Wiersum, Philip L. Llewellyn, Vincent Guillerm, Christian Serred, Guillaume Maurin; ChemComm, 2011, 47, 9603–9605; DOI ：10.1039/c1cc13543k; Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration；
5）Florence Ragon, Betiana Campo, Qingyuan Yang, Charlotte Martineau, Andrew D. Wiersum, Ana Lago, Vincent Guillerm, Callum Hemsley, Jarrod F. Eubank, Muthusamy Vishnuvarthan, Francis Taulelle, Patricia Horcajada, Alexandre Vimont, Philip L. Llewellyn, Marco Daturi, Sabine Devautour-Vinot, Guillaume Maurin, Christian Serre, Thomas Devic, Guillaume Clet； Journal of Materials Chemistry A, 2015, 3, 3294-3309; DOI：10.1039/c4ta03992k; Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties；
6) Shyam Biswas, Jian Zhang, Zhibao Li, Ying-Ya Liu, Maciej Grzywa, Lixian Sun, Dirk Volkmer, Pascal Van Der Voort; Dalton Transactions, 2013, 42, 4730-4737; DOI：10.1039/c3dt32288b; Enhanced Selectivity of CO₂ over CH₄ in Sulphonate-, Carboxylate- and Iodo-Functionalized UiO-66 Frameworks;
7) Shixiong Li, Shengli Sun, Haizhen Wu, Chaohai Wei, Yun Hu; Catalysis Science & Technology, 2018, 8, 1696-1703; DOI：10.1039/c7cy02622f; Effects of electron-donating groups on the photocatalytic reaction of MOFs;
8) Xudong Zhao, Yaxin Wang, Yali Li, Wenjuan Xue, Jian Li, Huiyuan Wu, Yuezhong Zhang, Bingzheng Li, Wen Liu, Zhuqing Gao, Hongliang Huang; Journal of Chemical & Engineering Data, 2019, 64, 2728-2735; DOI ：10.1021/acs.jced.9b00130; Synergy Effect of Pore Structure and Amount of Carboxyl Site for Effective Removal of Pb²⁺ in Metal−Organic Frameworks