NH2-UiO-66
NH2-UiO-66
CAS:1260119-00-3
M.F.:C48H34N6O32Zr6
M.W.:1754.15
Pricing
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Product: NH2-UIO-66(Zr)
Synonyms: NA
CAS：1260119-00-3
Basic Information
| Unit MF. | C48H34N6O32Zr6 | Unit MW. | 1754.15 | ||
| Coordination Metal | Zr | Linkers | 2-aminoterephthalic acid（CAS：10312-55-7） | ||
| Pore Size | 0.8nm; 1.1nm | Pore volume | 0.5 cm3/g | ||
| Surface Area | BET Specific surface 800 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Yellowish Powder |  |
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| Particle Size | 300-600nm | |||
Stability
1) NH2-UIO-66 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-12)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 6 hours at 120 degree in vacuum.
Other Features
Fluorescence: λem=456nm
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
2) NH2-UIO-66 has rigid framework, the amino group could be post-modified without destroying the framework of the material
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun. 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology；
3) Claudia Gomes Silva, Ignacio Luz, Francesc X. Labres i Xamena, Avelino Corma; CHEMISTRY A EUROPEAN JOURNAL, 2010, 16, 11133-11138; DOI：10.1002/chem.200903526; Water Stable Zr–Benzenedicarboxylate Metal–Organic Frameworks as Photocatalysts for Hydrogen Generation;
4) Jared B. DeCoste, Gregory W. Peterson, Himanshu Jasuja, T. Grant Glover, Yougui Huang, Krista S. Walton; Journal of Materials Chemistry A, 2013, 1, 5642-5650; DOI：10.1039/c3ta10662d; Stability and Degradation Mechanisms of Metal-Organic Frameworks containing the Zr₆O₄(OH)₄ Secondary Building Unit;
5) Gregory E. Cmarik, Min Kim, Seth M. Cohen, Krista S. Walton; Langmuir, 2012, 28, 15606-15613; DOI：10.1021/la3035352; Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization;
6) Shixiong Li, Shengli Sun, Haizhen Wu, Chaohai Wei, Yun Hu; Catalysis Science & Technology, 2018, 8, 1696-1703; DOI：10.1039/c7cy02622f; Effects of electron-donating groups on the photocatalytic reaction of MOFs