MIL-120(Al)
CAS:1200436-97-0
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Product: MIL-120(Al)
Synonyms: MIL-120(Al)-AP, MIL-120(Al)-HP
CAS：1200436-97-0
Basic Information
| Unit MF. | C10H2O16Al4.H2O | Unit MW. | 504.05456 | ||
| Coordination Metal | Al | Linkers |
benzene-1,2,4,5-tetracarboxylic acid |
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| Pore Size | ≈5.4 Å×4.7 Å | Pore volume | 0.151 cm³ g⁻¹ | ||
| Surface Area | ≈373m²/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | White Powders | |||
| Particle Size | MIL-120(Al)-HP is several microns; MIL-120(Al)-AP is about 300nm when using Al(OH)(CH₃COO)₂, and about 40-50nm when using NaAlO₂ | |||
Stability
1) It has excellent hydrolytic stability, can withstand boiling water for at least 10 days, with good retention of crystallinity and chemical composition
2) Good thermal stability, thermal decomposition temperature is around 400℃, the total decomposition temperature of MIL-120(Al)-AP is about 50℃ lower than that of MIL-120(Al)-HP
2) Good thermal stability, thermal decomposition temperature is around 400℃, the total decomposition temperature of MIL-120(Al)-AP is about 50℃ lower than that of MIL-120(Al)-HP
Preservation
1) Can be stored under normal temperature and dry conditions
2) It is recommended to activate under vacuum at 50℃ for 12 hours before use, or select appropriate activation temperature (such as 150℃) and time according to specific experimental needs
Other Features
fluorescence:NA
Applications
1) Used for post-combustion carbon capture, can efficiently separate CO₂ and N₂, with high CO₂ uptake at low pressure
2) Can be applied in carbon capture processes such as TSA and V/PSA, with low regeneration energy consumption, suitable for large-scale industrial applications
2) Can be applied in carbon capture processes such as TSA and V/PSA, with low regeneration energy consumption, suitable for large-scale industrial applications
Characterizations
References
1) Bingbing Chen, Dong Fan, Rosana V. Pinto, Iurii Dovgaliuk, Shyamapada Nandi, Debanjan Chakraborty, Nuria García-Moncada, Alexandre Vimont, Charles J. McMonagle, Marta Bordonhos, Abeer Al Mohtar, Ieuan Cornu, Pierre Florian, Nicolas Heymans, Marco Daturi, Guy De Weireld, Moisés Pinto, Farid Nouar, Guillaume Maurin, Georges Mouchaham, Christian Serre; Advanced Science, 2024, 11, 2401070, DOI: 10.1002/advs.202401070, A Scalable Robust Microporous Al-MOF for Post-Combustion Carbon Capture；
2）Volkringer, C.; Loiseau, T.; Haouas, M.; Taulelle, F.; Popov, D.; Burghammer, M.; Riekel, C.; Zlotea, C.; Cuevas, F.; Latroche, M.; Phanon, D.; Knöfel, C.; Llewellyn, P. L.; Férey, G. Chem. Mater. 2009, 21, 5783–5791. DOI:10.1021/cm9023106. Occurrence of Uncommon Infinite Chains Consisting of Edge-Sharing Octahedra in a Porous Metal–Organic Framework-Type Aluminum Pyromellitate Al₄(OH)₈[C₁₀O₈H₂] (MIL-120): Synthesis, Structure, and Gas Sorption Properties. ;
3) Zhang, P.; Zhong, Y.; Yao, Q.; Liu, X.; Zhang, Y.; Wang, J.; Deng, Q.; Zeng, Z.; Deng, S. J. Chem. Eng. Data 2020, 65, 4018–4023. DOI:10.1021/acs.jced.0c00323. Robust Ultramicroporous Metal−Organic Framework with Rich Hydroxyl-Decorated Channel Walls for Highly Selective Noble Gas Separation.