MIL-100(Fe)
MIL-100(Fe)
CAS:1195763-37-1
M.F.:C9H6O6Fe
M.W.:265.99
Pricing
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Product: MIL-100(Fe)
Synonyms: BASOLITE F300
CAS：947723-08-2 / 1195763-37-1
Basic Information
| Unit MF. | C18O15FFe3 | Unit MW. | 642.717 | ||
| Coordination Metal | Fe | Linkers | 1,3,5-Benzenetricarboxylic acid (CAS:554-95-0) | ||
| Aperture | Aperture:0.55-0.88nm; Pore Size: 2.5-2.9nm | Pore volume | 0.9 cm3/g (micropore vol. 0.55) | ||
| Surface Area | BET Specific surface 1900 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Orange Powder |  |
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| Particle Size | 1-10um particles or clusters | |||
Stability
1) MIL-100(Fe) is stable in air, stable in aqueous and acidic conditions(PH1-12)
2）Thermal decomposition temperature above 280 ° C
2）Thermal decomposition temperature above 280 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Lewis acid catalyst
2) Lewis acid catalyst
Characterizations
References
1) P. Horcajada, S. Surble, C. Serre, D.-Y. Hong, Y.-K. Seo, J.-S. Chang, J.-M. Greneche, I. Margiolaki, G. Férey, Chem. Commun., 2007, 2820-2822, DOI: 10.1039/B704325B Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores;
2) You-Kyong Seo, Ji Woong Yoon, Ji Sun Lee, U-Hwang Lee, Young Kyu Hwang, Chul-Ho Jun, Patricia Horcajada, Christian Serre, Jong-San Chang. Microporous and Mesoporous Materials, 2012, 157. DOI:10.1016/j.micromeso.2012.02.027. Large scale fluorine-free synthesis of hierarchically porous iron(Ⅲ) trimesate MIL-100(Fe) with a zeolite MTN topology.；
3）Pia Küsgens , Marcus Rose , Irena Senkovska , Heidrun Fröde , Antje Henschel , Sven Siegle , Stefan Kaskel ；Volume 120, Issue 3, 15 April 2009, Pages 325-330；doi:10.1016/j.micromeso.2008.11.020；Characterization of metal-organic frameworks by water adsorption；
4）Camille Petit and Teresa J. Bandosz *；Adv. Funct. Mater. 2011, 21, 2108–2117；DOI: 10.1002/adfm.201002517. Synthesis, Characterization, and Ammonia Adsorption Properties of Mesoporous Metal–Organic Framework (MIL(Fe))–Graphite Oxide Composites: Exploring the Limits of Materials Fabrication；
5) Guesh, Kiros; Caiuby, Clarice A. D.; Mayoral, Alvaro ; Diaz-Garcia, Manuel; Diaz, Isabel; Sanchez-Sanchez, Manuel；Crystal Growth & Design 2017 , 17(4), 1806-1813；DOI：10.1021/acs.cgd.6b01776；Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water；
5） Dongbo Wang, Feiyue Jia, Hou Wang, Fei Chen, Ying Fang, Wenbo Dong, Guangming Zeng, Xiaoming Li, Qi Yang, Xingzhong Yuan. Journal of Colloid and Interface Science, 2018, volume, issue. DOI:10.1016/j.jcis.2018.02.067. Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs.