CAS 1012075-54-5|bimx|BTIB|p-tmbix|p-bitmb|CHEMSOON-MOF/COFmaterial professional supplier

Product Name：1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
Synonymous：bimx ; BTIB ; p-tmbix ; p-bitmb;1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-imidazole]
CAS：1012075-54-5

Basic Info

M.F.	C18H22N4		M.W.	294.39408
Appearance

Properties

1) It is soluble in DMF and DMSO
2) Sealed at room temperature

Appications

1) It could be used as monomer linker for MOF synthesis:[Zn(bdc)(bimx)] [r1]; [Cu(CO3)(btib)] [r2]; [Cd(BDC)(m-bitmb)(H2O)] [r4]

Characterization

HNMR

FTIR

HPLC

Reference

1) Schaate, Andreas; Klingelhoefer, Stefan; Behrens, Peter; Wiebcke, Michael; Cryst. Growth & Des. 2008, 8(9), 3200-3205, DOI: 10.1021/cg701041k ; Two Zinc(II) Coordination Polymers Constructed with Rigid 1,4-Benzenedicarboxylate and Flexible 1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene Linkers: From Interpenetrating Layers to Templated 3D Frameworks

2) Inoue, Tatsunari; Yamanishi, Katsunori; Kondo, Mitsuru; Inorg. Chem. 2013, 52(9), 4765-4767,DOI: 10.1021/ic400315g ; Solvent-Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2- Unit

3) Kose Yaman, Pelin; Arici, Mursel; Erer, Hakan; Yesilel, Okan Zafer; J. Mole. Struct. 2021, 1229, 129499, DOI: 10.1016/j.molstruc.2020.129499 ; The Effect of Metal Salts on The Structures of 2,2-Dimethylglutarate Complexes with a Flexible 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene

4) Zhang, Yan; Luo, Wenping; Liu, Dongju; Xu, Yan; Li, Shun-Li; Li, Jingfu; Wu, Yong; Zhou, Yaoming; Fang, Min; Liu, Hong-Ke; Inorg. Chimi. Acta 2014, 409(PB), 512-517, DOI: 10.1016/j.ica.2013.09.043 ; Structures and photoluminescence properties of two cadmium(II) coordination polymers synthesized by flexible and rigid ligands