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Boronic acid, B,​B',​B'',​B'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayltetra-​4,​1-​phenylene)​tetrakis-
Boronic acid, B,​B',​B'',​B'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayltetra-​4,​1-​phenylene)​tetrakis-
CAS:97654-08-5 M.F.:C44H34B4N4O8 M.W.:790.00676
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Product Name:5,​10,​15,​20-​Tetrakis(4-​boronylphenyl)​porphyrin
Synonymous:H2TBPP; TDHB;Boronic acid, B,​B',​B'',​B'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayltetra-​4,​1-​phenylene)​tetrakis-
CAS:97654-08-5
Basic Info
M.F. C44H34B4N4O8 M.W. 790.00676
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:COF-66 [r1]; MP-COF M=H, Zn, Cu [r2,r3]
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Wan, S.; Gandara, F.; Asano, A.; Furukawa, H.; Saeki, A.; Dey, S.; Liao, L.; Ambrogio, M.; Botros, Y.; Duan, X.; Seki, S.; Stoddart, J.; Yaghi, O.  Chem. Mater., 2011, 23, 4094– 4097, DOI:10.1021/cm201140r ; Covalent Organic Frameworks with High Charge Carrier Mobility 
2) Feng, X.; Chen, L.; Dong, Y.; Jiang, D.; Chem. Commun., 2011,47, 1979-1981, DOI: 10.1039/C0CC04386A ; Porphyrin-based two-dimensional covalent organic frameworks: synchronized synthetic control of macroscopic structures and pore parameters  
3) Feng, X.; Liu, L.; Honsho, Y.; Saeki, A.; Seki, S.; Irle, S.; Dong, Y.; Nagai, A.; Jiang, D.; Angew. Chem., Int. Ed. 2012, 51(11), 2618-2622, DOI: 10.1002/ange.201106203 ; High‐Rate Charge‐Carrier Transport in Porphyrin Covalent Organic Frameworks: Switching from Hole to Electron to Ambipolar Conduction
97654-08-5-CS014906.pdf Download
97654-08-5-CS014931.pdf Download
Boronic acid, B,​B',​B'',​B'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayltetra-​4,​1-​phenylene)​tetrakis-
Boronic acid, B,​B',​B'',​B'''-​(21H,​23H-​porphine-​5,​10,​15,​20-​tetrayltetra-​4,​1-​phenylene)​tetrakis-

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