Product: NKCOF-62
Synonyms: g-PzD-COF,COF-TMPyrz-DFB;COF-TMP;TMPZ-TPA COF;1,4-Benzenedicarboxaldehyde, polymer with tetramethylpyrazine
CAS:96361-32-9
Basic Information
Unit MF. |
C8H12N2.C8H6O2 |
Unit MW. |
270.33 |
Linkers |
1) 2,3,5,6-Tetramethylpyrazine (CAS: 1124-11-4); 2) Terephthalaldehyde(CAS: 623-27-8) |
Pore Size |
0.7 nm |
Pore volume |
0.59 cm3/g |
Surface Area |
700 m2/g |
Analog Structure |
 |
Product Property
Stability
1) Thermogravimetric analysis (TGA) of NKCOF-62 under nitrogen atmosphere showed thermal stability up to 400 ° C.
2) After soaking in boiling water, 12 M HCl, and 10 M NaOH for 7 days, NKCOF-62 maintained its original PXRD mode and exhibited good chemical stability.
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 120 degree in vacuum before gas adsorption.
Other Features
Fluorescence: NA
Applications
Characterizations
References
1) Zhifang Wang, Yushu Zhang, En Lin, Shubo Geng, Mengjin Wang, Jinjin Liu, Yao Chen, Peng Cheng, and Zhenjie Zhang*;J. Am. Chem. Soc. 2023, 145, 21483−21490; DOI: 10.1021/jacs.3c07224; Kilogram-Scale Fabrication of a Robust Olefin-Linked Covalent Organic Framework for Separating Ethylene from a Ternary C2 Hydrocarbon Mixture;