Home > Product Category > MOF Chemicals > Carboxylic MOFs Linkers > 4d-Carboxylic MOF Linkers
Add to Favorites
1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
CAS:957014-40-3 M.F.:C26H14O8 M.W.:454.38456
Pricing //
Product Name:1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
Synonymous:TCB ; H4TCB ; PDEB;5,​5'-​(1,​4-​Phenylenedi-​2,​1-​ethynediyl)​bis[1,​3-​benzenedicarboxylic acid]
CAS:957014-40-3
Basic Info
M.F. C26H14O8 M.W. 454.38456
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:NJU-Bai12 [r4]; UHM-8 , UHM-9 [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Daniell, Heather W.; Klotz, Eric J. F.; Odell, Barbara; Claridge, Tim D. W.; Anderson, Harry L.; Angew. Chem., Int. Ed. 2007, 46(36), 6845-6848, DOI: 10.1002/anie.200702349 ; Solid-​phase synthesis of oligo(phenylene ethynylene) rotaxanes
2) Zhou, Hui; Dang, Hung; Yi, Ji-Hyun; Nanci, Antonio; Rochefort, Alain; Wuest, James D.; Journal of the American Chemical Society 2007, 129(45), 13774-13775, DOI: 10.1021/ja0742535 ; Frustrated 2D Molecular Crystallization
3) Zhao, Jian-Feng; Li, Yi-Bao; Lin, Zong-Qiong; Xie, Ling-Hai; Shi, Nai-En; Wu, Xing-Kui; Wang, Chen; Huang, Wei; J. Phys. Chem. C 2010, 114(21), 9931-9937, DOI: 10.1021/jp1022482 ; Molecule Length Directed Self-​Assembly Behavior of Tetratopic Oligomeric Phenylene-​Ethynylenes End-​Capped with Carboxylic Groups by Scanning Tunneling Microscopy
4) Zheng, Baishu; Yun, Ruirui; Bai, Junfeng; Lu, Zhiyong; Du, Liting; Li, Yizhi; Inorg. Chem. 2013, 52(6), 2823-2829, DOI :10.1021/ic301598n ; Expanded Porous MOF-​505 Analogue Exhibiting Large Hydrogen Storage Capacity and Selective Carbon Dioxide Adsorption

5) Frahm, Daniela; Hoffmann, Frank; Froeba, Michael; Cryst. Growth & Des. 2014, 14(4), 1719-1725, DOI: 10.1021/cg4018536 ; Two Metal-​Organic Frameworks with a Tetratopic Linker: Solvent-​Dependent Polymorphism and Postsynthetic Bromination

1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene
1,4-Di((3,5-dicarboxyphenyl)ethynyl)benzene

OK