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4,​4''-​diethenyl-​5'-​(4-​ethenylphenyl)​-1,​1':3',​1''-​Terphenyl
4,​4''-​diethenyl-​5'-​(4-​ethenylphenyl)​-1,​1':3',​1''-​Terphenyl
CAS:944155-02-6 M.F.:C30H24 M.W.:384.51156
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Product Name:1,​3,​5-​Tris(4-​ethenylphenyl)​benzene
Synonymous:TEPB; TVPB;4,​4''-​Diethenyl-​5'-​(4-​ethenylphenyl)​-​1,​1':3',​1''-​terphenyl; 1,​3,​5-​Tri(4-​vinylphenyl)​benzene
CAS:944155-02-6
Basic Info
M.F. C30H24 M.W. 384.51156
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:
2) It can be used to synthesize luminescent microporous org. Polymers lmop-1,2,3 [R2]; TPV network
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Terenziani, Francesca; Le Droumaguet, Celine; Katan, Claudine; Mongin, Olivier; Blanchard-Desce, Mireille; ChemPhysChem 2007, 8(5), 723-734, DOI: 10.1002/cphc.200600689 ; Effect of branching on two-​photon absorption in triphenylbenzene derivatives
2) Sun, Libo; Liang, Zhiqiang; Yu, Jihong; Xu, Ruren; Polym. Chem. 2013, 4(6), 1932-1938, DOI: 10.1039/c2py21034g ; Luminescent microporous organic polymers containing the 1,​3,​5-​tri(4-​ethenylphenyl)​benzene unit constructed by Heck coupling reaction
3) Gopalakrishnan, Deepti; Dichtel, William R.; Journal of the American Chemical Society 2013, 135(22), 8357-8362, DOI: 10.1021/ja402668e ; Direct Detection of RDX Vapor Using a Conjugated Polymer Network
4) Li, Cunyao; Sun, Keju; Wang, Wenlong; Yan, Li; Sun, Xueping; Wang, Yuqing; Xiong, Kai; Zhan, Zhuangping; Jiang, Zheng; Ding, Yunjie; J. Catal. 2017, 353, 123-132, DOI: 10.1016/j.jcat.2017.07.022 ; Xantphos doped Rh​/POPs-​PPh3 catalyst for highly selective long-​chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh3
4,​4''-​diethenyl-​5'-​(4-​ethenylphenyl)​-1,​1':3',​1''-​Terphenyl
4,​4''-​diethenyl-​5'-​(4-​ethenylphenyl)​-1,​1':3',​1''-​Terphenyl

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