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PICOF-2
PICOF-2
CAS:932735-93-8
M.F.:(C24H21N3.C10H2O6)X
M.W.:569.56
Pricing
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Product: PICOF-2
Synonyms: 1H,3H-Benzo[1,2-c:4,5-c′]difuran-1,3,5,7-tetrone, polymer with 5′-(4-aminophenyl)[1,1′:3′,1′′-terphenyl]-4,4′′-diamine；PMDA-TAPB-COF；TPP-PMDA-COF
CAS：932735-93-8
Basic Information
| Unit MF. | C24H21N3.C10H2O6 | Unit MW. | 569.56 | ||
| Linkers | 1,3,5-Tris(4-aminophenyl)benzene(CAS: 118727-34-7); Pyromellitic Dianhydride(CAS:89-32-7) | ||||
| Pore Size | 3.6 nm | Pore volume | 0.31cm3 /g | ||
| Surface Area | BET 600-1000m2/g |
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| Analog Structure |  |
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Product Property
| Appearance | Yellow microcrystalline powder | |||
| Particle Size | irregular nanoparticle clusters | |||
Stability
1) PICOF-2 is stable in sealed condition for weeks, and stable in water and common organic solvent
2) Thermally stable, thermal decomposition temperature of PICOF-2 is above 530° C
2) Thermally stable, thermal decomposition temperature of PICOF-2 is above 530° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 150 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas and pollutant adsorption
2) With stable channel of 3.3nm, PICOF-2 is a potential carrier of catalyst and prospective in enzyme encapsulation
2) With stable channel of 3.3nm, PICOF-2 is a potential carrier of catalyst and prospective in enzyme encapsulation
Characterizations
References
1) Li, Guiyang; Wang, Zhonggang; Macromolecules (Washington, DC, United States) 2013 , 46(8), 3058-3066; DOI: 10.1021/ma400496q; Microporous Polyimides with Uniform Pores for Adsorption and Separation of CO2 Gas and Organic Vapors
2) Zhang, Zhenjie; Wang, Zhifang; Zhao, Zhengfeng; Chen, Yao; China, CN114773556 A 2022-07-22; Green solid phase synthesis method covalent organic framework material; 一种共价有机框架材料的绿色固相合成方法
3) Van der Jagt, Remco ; Vasileiadis, Alexandros; Veldhuizen, Hugo ; Shao, Pengpeng; Feng, Xiao ; Ganapathy, Swapna; Habisreutinger, Nicolas C.; van der Veen, Monique A. ; Wang, Chao; Wagemaker, Marnix ; et al; Chemistry of Materials 2021 , 33(3), 818-833; DOI: 10.1021/acs.chemmater.0c03218; Synthesis and Structure-Property Relationships of Polyimide Covalent Organic Frameworks for Carbon Dioxide Capture and (Aqueous) Sodium-Ion Batteries
2) Zhang, Zhenjie; Wang, Zhifang; Zhao, Zhengfeng; Chen, Yao; China, CN114773556 A 2022-07-22; Green solid phase synthesis method covalent organic framework material; 一种共价有机框架材料的绿色固相合成方法
3) Van der Jagt, Remco ; Vasileiadis, Alexandros; Veldhuizen, Hugo ; Shao, Pengpeng; Feng, Xiao ; Ganapathy, Swapna; Habisreutinger, Nicolas C.; van der Veen, Monique A. ; Wang, Chao; Wagemaker, Marnix ; et al; Chemistry of Materials 2021 , 33(3), 818-833; DOI: 10.1021/acs.chemmater.0c03218; Synthesis and Structure-Property Relationships of Polyimide Covalent Organic Frameworks for Carbon Dioxide Capture and (Aqueous) Sodium-Ion Batteries
| XRD PICOF-2 CS018159.pdf | Download |