Home > Product Category > MOF Chemicals > Carboxylic MOFs Linkers > 2d-Carboxylic MOF Linkers > Biphenyl-dicarboxylic Linkers
[1,1'-Biphenyl]-4,4'-dicarboxylic acid, 2,2'-bis(trifluoromethyl)-
[1,1'-Biphenyl]-4,4'-dicarboxylic acid, 2,2'-bis(trifluoromethyl)-
CAS:89803-71-4
M.F.:C16H8F6O4
M.W.:378.222745895386
Pricing
//
Product Name：2,2′-bis(trifluoromethyl)-4,4′-biphenyldicarboxylic acid
Synonymous：H2BPDC-m-2CF3;
CAS：89803-71-4
3) Chen, Cheng-Xia; Qiu, Qian-Feng; Pan, Mei; Cao, Chen-Chen; Zhu, Neng-Xiu; Wang, Hai-Ping; Jiang, Ji-Jun; Wei, Zhang-Wen; Su, Cheng-Yong; Chem. Commun. 2018, 54(97), 13666-13669, DOI: 10.1039/c8cc07441k ; Tunability of fluorescent metal-organic frameworks through dynamic spacer installation with multivariate fluorophores
Synonymous：H2BPDC-m-2CF3;
CAS：89803-71-4
Basic Info
| M.F. | C16H8O4F6 | M.W. | 378.22272 | ||
| Appearance |  |
||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：UiO-67-m-2CF3 [r1]; LIFM-28 [r3]; LIFM-100 [r4, r5]; PCN-700[r6]
Characterization
Reference
1) Wang, Keke; Huang, Hongliang; Zhou, Xiaocong; Wang, Qin; Li, Guijie; Shen, Haimin; She, Yuanbin; Zhong, Chongli; Inorg. Chem. 2019, 58(9), 5725-5732, DOI: 10.1021/acs.inorgchem.9b00088 ; Highly Chemically Stable MOFs with Trifluoromethyl Groups: Effect of Position of Trifluoromethyl Groups on Chemical Stability
2) gers, H. G.; Gaudiana, Russell A.; Hollinsed, W. C.; Kalyanaraman, P. S.; Manello, J. S.; McGowan, C.; Minns, R. A.; Sahatjian, R.; Macromolecules 1985, 18(6), 1058-1068, DOI: 10.1021/ma00148a003 ; Highly amorphous, birefringent, para-linked aromatic polyamides4) Qiu, Qian-feng; Chen, Cheng-Xia; Wei, Zhang-Wen; Cao, Chen-Chen; Zhu, Neng-Xiu; Wang, Hai-Ping; Wang, Dawei; Jiang, Ji-Jun; Su, Cheng-Yong; Inorg. Chem. 2019, 58(1), 61-64, DOI: 10.1021/acs.inorgchem.8b02993 ; A Flexible Cu-MOF as Crystalline Sponge for Guests Determination
5) Qiu, Qian-Feng; Chen, Cheng-Xia; Zeng, Zheng; Wei, Zhang-Wen; Zhu, Neng-Xiu; Cao, Chen-Chen; Wang, Wei; Wang, Dawei; Wang, Hai-Ping; Jiang, Ji-Jun; Inorg. Chem. 2020, 59(20), 14856-14860, DOI: 10.1021/acs.inorgchem.0c02123 ; A Flexible-Robust Copper(II) Metal-Organic Framework Constructed from a Fluorinated Ligand for CO2/R22 Capture
6) Fan Yang, Jiajia Wang, You Wang, Benling Yu, Yiwen Cao, Jiawei Li, Linlin Wu, Jianhan Huang, You-Nian Liu; Angew. Chem. Int. Ed. DOI: 10.1002/anie.202318115, Perfluoroalkyl-Decorated Noble-Metal-Free MOFs for the Highly Efficient One-Pot Four-Component Coupling between Aldehydes, Amines, Alkynes, and Flue Gas CO2
| 89803-71-4-CS017774.pdf | Download |