Product: PI-COF 201
Synonyms: 1H,3H-Benzo[1,2-c:4,5-c′]difuran-1,3,5,7-tetrone, polymer with 1,3,5-triazine-2,4,6-triamine
CAS:89698-81-7
Basic Information
Unit MF. |
C10H2O6.C3H6N6 |
Unit MW. |
344.239 |
Linkers |
1) 1,3,5-Triazine-2,4,6-triamine(CAS: 108-78-1);
2) Pyromellitic dianhydride(CAS:89-32-7)
|
Pore Size |
nm |
Pore volume |
The total pore volume is 0.60 cm3 /g, and the micropore volume is 0.21 cm3 /g |
Surface Area |
The BET specific surface area is approximately 600-800 m2/g |
Analog Structure |
|
Product Property
Stability
1) Its thermogravimetric analysis (TGA) under a nitrogen atmosphere showed that it only began to rapidly lose weight above 400 ° C, demonstrating excellent thermal stability.
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 100 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Due to its high specific surface area and pore structure, it may be suitable for gas storage, such as hydrogen and carbon dioxide storage;
2) Considering its high thermal stability and good chemical resistance, it may also be suitable as an adsorbent for separating CO2 from flue gas, as well as other applications that require highly stable porous materials.
Characterizations
References
1) Yali Luo, Buyi Li, Liyun Liang and Bien Tan*; Chem. Commun., 2011,47, 7704-7706; DOI: 10.1039/c1cc11466b; Synthesis of cost-effective porous polyimides and their gas storage propertiesw;
2) He Sun, Cheng Wang, Xiao Zhang, and Fengwei Wang,*; J Mater Sci 59, 9319–9332 ,2024; DOI:10.1007/s10853-024-09776-1; Preparation of polyimide bond‑linked covalent organic frameworks as resin‑compatible nanofillers for copper clad laminates with improved thermal and electrical performances;