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3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl
3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl
CAS:868046-56-4 M.F.:C46H38O8 M.W.:718.78912
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Product Name:3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl
Synonymous:H4TCHB; H4TTTA;
CAS:868046-56-4
Basic Info
M.F. C46H38O8 M.W. 718.78912
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:MFM-​133(M) (M = Zr, Hf) [r2]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Moorthy, J.; Natarajan, R.; Venugopalan, P.; J. Org. Chem. 2005, 70(21), 8568-8571, DOI: 10.1021/jo051205z ; Three-Dimensional Four-Connecting Organic Scaffolds with a Twist:  Synthesis and Self-Assembly 
2) Yan, Y.; O'Connor, A.; Kanthasamy, G.; Atkinson, G.; Allan, D.; Blake, A.; Schroder, M.; J. Am. Chem. Soc. 2018, 140(11), 3952-3958, DOI: 10.1021/jacs.7b11747 ; Unusual and Tunable Negative Linear Compressibility in the Metal–Organic Framework MFM-133(M) (M = Zr, Hf) 
3) Lv, X.; Yuan, S.; Xie, L.; Darke, H.; Chen, Y.; He, T.; Dong, C.; Wang, B.; Zhang, Y.; Li, J.; Zhou, H.; J. Am. Chem. Soc. 2019, 141(26), 10283-10293, DOI:10.1021/jacs.9b02947 ; Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks 
868046-56-4-CS017591.pdf Download
3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl
3,​3',​5,​5'-​tetrakis(4-​carboxyphenyl)​-​2,​2',​4,​4',​6,​6'-​hexamethyl-​1,​1'-​biphenyl

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