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MIL-100(Cr)
MIL-100(Cr)
CAS:840523-88-8 M.F.:C18H10Cr3FO15 M.W.:641.25
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Product: MIL-100(Cr) 
Synonyms: NA
CAS:840523-88-8

Basic Information
Unit MF. C18O15FCr3.O Unit MW. 647.1697
Coordination  Metal Cr Linkers 1,3,5-Benzenetricarboxylic acid (CAS:554-95-0)
Aperture Aperture:0.55-0.88nm; Pore Size: 2.5-2.9nm Pore volume 0.9 cm3/g (micropore vol. 0.55)
Surface Area BET Specific surface 2000 m2/g
Analog Structure  
Product Property
Appearance Orange Powder
Particle Size 300-600nm
Stability
1) MIL-100(Cr) is stable in air, stable in aqueous and acidic conditions(PH1-12)
2)Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant adsorption
2) Aperture size proper for drug carrier
Characterizations
XRD
XRD-MIL-100-Cr
BET
BET-MIL-300-Cr
SEM
SEM-MIL-100(Cr)
FTIR
NA
References
1) Horcajada, P.; Serre, C.; Vallet-Regi, M.; Sebban, M.; Taulelle, F.; Férey, G. Angew. Chem. Int. Ed. 2006, 45(36), 5974-5978; DOI: 10.1002/anie.200601878 ; Metal–Organic Frameworks as Efficient Materials for Drug Delivery
2) Vimont, Alexandre; Goupil, Jean-Michel; Lavalley, Jean-Claude; Daturi, Marco; Surble, Suzy; Serre, Christian; Millange, Franck; Ferey, Gerard; Audebrand, Nathalie; J. Am. Chem. Soc. 2006, 128, 10, 3218–3227, DOI: 10.1021/ja056906s ; Investigation of Acid Sites in a Zeotypic Giant Pores Chromium(III) Carboxylate
3) Ferey, Gerard; Serre, Christian; Mellot-Draznieks, Caroline; Millange, Franck; Surble, Suzy; Dutour, Julien; Margiolaki, Irene; Angewandte Chemie, International Edition 2004, 43(46), 6296-6301, DOI: 10.1002/anie.200460592 ; Molecular modeling: A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction

 

MIL-100(Cr)
MIL-100(Cr)

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