Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]-, 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene
Benzene, 1,1',1'',1'''-(1,2-ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]-, 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene
CAS:741259-14-3
M.F.:C46H52Si4
M.W.:717.24708
Pricing
//
Product Name：Tetrakis(trimethylsilylethynylphenyl)ethylene
Synonymous：TPE-(TMS)4;Silane, [1,2-ethenediylidenetetrakis(4,1-phenylene-2,1-ethynediyl)]tetrakis[trimethyl- (9CI); 1,1',1'',1'''-(1,2-Ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]benzene]; 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene;
CAS：741259-14-3
3) Yuan, Kai; Guo-Wang, Peiyao; Hu, Ting; Shi, Lei; Zeng, Rong; Forster, Michael; Pichler, Thomas; Chen, Yiwang; Scherf, Ullrich; Chem. Mater. 2015, 27, 21, 7403-7411, DOI: 10.1021/acs.chemmater.5b03290 ; Nanofibrous and Graphene-Templated Conjugated Microporous Polymer Materials for Flexible Chemosensors and Supercapacitors
Synonymous：TPE-(TMS)4;Silane, [1,2-ethenediylidenetetrakis(4,1-phenylene-2,1-ethynediyl)]tetrakis[trimethyl- (9CI); 1,1',1'',1'''-(1,2-Ethenediylidene)tetrakis[4-[2-(trimethylsilyl)ethynyl]benzene]; 1,1,2,2-Tetrakis(4-((trimethylsilyl)ethynyl)phenyl)ethene;
CAS：741259-14-3
Basic Info
| M.F. | C46H52Si4 | M.W. | 717.24708 | ||
| Appearance | |||||
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis：Conjugated microporous polymers (CMPs) PTEPE-TBPE
Characterization
Reference
1) Sengupta, Saumitra; Synlett 2004, (7), 1191-1194, DOI: 10.1055/s-2004-822929 ; Synthesis of highly conjugated two-dimensional molecular scaffolds via Pd-catalyzed reactions on a tetraphenylethylene core
2) Wang, Jian; Mei, Ju; Zhao, Engui; Song, Zhegang; Qin, Anjun; Sun, Jing Zhi; Tang, Ben Zhong; Macromolecules 2012, 45(19), 7692-770, DOI: 10.1021/ma3017037 ; Ethynyl-Capped Hyperbranched Conjugated Polytriazole: Click Polymerization, Clickable Modification, and Aggregation-Enhanced Emission4) Ramachandran, Elumalai; Dhamodharan, Raghavachari; J. Mater. Chem. C 2017, 5(40), 10469-10476, DOI: 10.1039/C7TC03211K ; Tetrakis(trialkylsilylethynylphenyl)ethenes: mechanofluorochromism arising from steric considerations with an unusual crystal structure
5) Wang, Zheng; Zhu, Cheng-Yi; Mo, Jun-Ting; Fu, Peng-Yan; Zhao, Yan-Wu; Yin, Shao-Yun; Jiang, Ji-Jun; Pan, Mei; Su, Cheng-Yong; Angew. Chem., Int. Ed. 2019, 58(29), 9752-9757, DOI: 10.1002/anie.201905186 ; White-Light Emission from Dual-Way Photon Energy Conversion in a Dye-Encapsulated Metal-Organic Framework