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5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)
5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)
CAS:705930-83-2 M.F.:C45H42O6 M.W.:678.81138
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Product Name:3,​3',​3''-​(1,​3,​5-​Benzenetriyltri-​2,​1-​ethynediyl)​tris[5-​(1,​1-​dimethylethyl)​-​6-​hydroxybenzaldehyde]
Synonymous:
CAS:705930-83-2
Basic Info
M.F. C45H42O6 M.W. 678.81138
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:salenCOF [r3]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Nielsen, Morten; Thomsen, Anne H.; Jensen, Torben R.; Jakobsen, Hans J.; Skibsted, Jorgen; Gothelf, Kurt V.; Eur. J. Org. Chem. 2005, (2), 342-347, DOI: 10.1002/ejoc.200400451 ; Formation and structure of conjugated salen-​cross-​linked polymers and their application in asymmetric heterogeneous catalysis
2) Weigelt, Sigrid; Bombis, Christian; Busse, Carsten; Knudsen, Martin M.; Gothelf, Kurt V.; Laegsgaard, Erik; Besenbacher, Flemming; Linderoth, Trolle R.; ACS Nano 2008, 2(4), 651-660, DOI: 10.1021/nn7004365 ; Molecular Self-​Assembly from Building Blocks Synthesized on a Surface in Ultrahigh Vacuum: Kinetic Control and Topo-​Chemical Reactions
3) Li, Li-Hua; Feng, Xiao-Lin; Cui, Xiao-Hui; Ma, Yun-Xiang; Ding, San-Yuan; Wang, Wei.; J. Am. Chem. Soc. 2017, 139(17), 6042-6045, DOI: 10.1021/jacs.7b01523 ; Salen-​Based Covalent Organic Framework
4) Kannan, Masanam; De, Pinaki Bhusan; Pradhan, Sourav; Punniyamurthy, Tharmalingam; ChemistrySelect 2018, 3(3), 859-863, DOI: 10.1002/slct.201702607 ; Chiral Fe-​Dendrimer-​Catalyzed Domino Michael and Aldol Reactions of Chalcones with 1,​4-​Dithiane-​2,​5-​diol
5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)
5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(3-(tert-butyl)-2-hydroxybenzaldehyde)

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