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Biphenyl-4,4'-dithiol
Biphenyl-4,4'-dithiol
CAS:6954-27-4 M.F.:C12H10S2 M.W.:218.3378
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Product Name:[1,​1'-​Biphenyl]​-​4,​4'-​dithiol
Synonymous:H2bpdt;4,​4'-​Biphenyldithiol; 4,​4'-​Dimercaptobiphenyl; 4,​4'-​Dimercaptodiphenyl; 4,​4'-​Diphenyldithiol
CAS:6954-27-4
Basic Info
M.F. C12H10S2 M.W. 218.3378
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Cd(en)​3]​[Cd(bpdt)​2]​(en)​ [r1];
2) It can be used as polymer crosslinker or biological crosslinker
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Louvain, Nicolas; Takashima, Yohei; Kitagawa, Susumu; Furukawa, Shuhei; New J. Chemistry . 2011, 35(6), 1265-1269, DOI: 10.1039/c1nj20042a ; Thermodynamically controlled coordination-​engineering of novel 2D cadmium thiolate coordination polymers
2) Andres, Ronald P.; Bein, Thomas; Dorogi, Matt; Feng, Sue; Henderson, Jason I.; Kubiak, Clifford P.; Mahoney, William; Osifchin, Richard G.; Reifenberger, R.; Science 1996, 272(5266), 1323-1325, DOI: 10.1126/science.272.5266.1323 ; "Coulomb staircase" at room temperature in a self-​assembled molecular nanostructure
3) Reddy, Pramod; Jang, Sung-Yeon; Segalman, Rachel A.; Majumdar, Arun; Science 2007, 315(5818), 1568-1571, DOI: 10.1126/science.1137149 ; Thermoelectricity in Molecular Junctions
4) Tour, James M.; Jones, LeRoy, II; Pearson, Darren L.; Lamba, Jaydeep J. S.; Burgin, Timothy P.; Whitesides, George M.; Allara, David L.; Parikh, Atul N.; Atre, Sundar; J. Am. Chem. Soc. 1995, 117(37), 9529-9534, DOI: 10.1021/ja00142a021 ; Self-​Assembled Monolayers and Multilayers of Conjugated Thiols, α,​ω-​Dithiols, and Thioacetyl-​Containing Adsorbates. Understanding Attachments between Potential Molecular Wires and Gold Surfaces

5) Dadosh, Tali; Gordin, Yoav; Krahne, Roman; Khivrich, Ilya; Mahalu, Diana; Frydman, Veronica; Sperling, Joseph; Yacoby, Amir; Bar-Joseph, Israel; Nature 2005, 436(7051), 677-680, DOI: 10.1038/nature03898 ; Measurement of the conductance of single conjugated molecules

Biphenyl-4,4'-dithiol
Biphenyl-4,4'-dithiol

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