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4,​4',​4'',​4''',​4'''',​4'''''-​(1,​2,​3,​4,​5,​6-​benzenehexaylhexa-​2,​1-​ethynediyl)​hexakis-Benzoic acid
4,​4',​4'',​4''',​4'''',​4'''''-​(1,​2,​3,​4,​5,​6-​benzenehexaylhexa-​2,​1-​ethynediyl)​hexakis-Benzoic acid
CAS:684216-81-7 M.F.:C60H30O12 M.W.:942.873
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Product Name:hexakis(4-carboxyphenylethynyl)benzene
Synonymous:HCEB;Benzoic acid, 4,​4',​4'',​4''',​4'''',​4'''''-​(1,​2,​3,​4,​5,​6-​benzenehexaylhexa-​2,​1-​ethynediyl)​hexakis-
CAS:684216-81-7
Basic Info
M.F. C60H30O12 M.W. 942.873
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:HOF-​76 [r2]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Kobayashi, Kenji; Kobayashi, Norifumi; J. Org. Chem. 2004, 69(7), 2487-2497, DOI: 10.1021/jo049948s ; Synthesis and Self-​Association, Absorption, and Fluorescence Properties of Differentially Functionalized Hexakis(p-​substituted-​phenylethynyl)​benzenes
2) Zhang, Xu; Li, Libo; Wang, Jia-Xin; Wen, Hui-Min; Krishna, Rajamani; Wu, Hui; Zhou, Wei; Chen, Zhong-Ning; Li, Bin; Qian, Guodong; Chen, Banglin; Journal of the American Chemical Society 2020, 142(1), 633-640, DOI: 10.1021/jacs.9b12428 ; Selective Ethane​/Ethylene Separation in a Robust Microporous Hydrogen-​Bonded Organic Framework
4,​4',​4'',​4''',​4'''',​4'''''-​(1,​2,​3,​4,​5,​6-​benzenehexaylhexa-​2,​1-​ethynediyl)​hexakis-Benzoic acid
4,​4',​4'',​4''',​4'''',​4'''''-​(1,​2,​3,​4,​5,​6-​benzenehexaylhexa-​2,​1-​ethynediyl)​hexakis-Benzoic acid

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