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[2,2'-Bipyridine]-4,4'-dicarboxylic acid
[2,2'-Bipyridine]-4,4'-dicarboxylic acid
CAS:6813-38-3 M.F.:C12H8N2O4 M.W.:244.20292
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Product Name:[2,2'-Bipyridine]-4,4'-dicarboxylic acid
Synonymous:2,​2'-​bipyridyl-​4,​4'-​dicarboxylic acid,H2dcbp; 4,4'-H2dcbp; BPDC
CAS:6813-38-3
Basic Info
M.F.  C12H8N2O4 M.W.  244.20292
Appearance
Properties
1)  It is soluble in DMF, DMSO, etc.
2)  Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: [Ln(BPDC)​1.5(DMF)​(H2O)​2] [r4] etc.
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Tynan, Eithne; Jensen, Paul; Kruger, Paul E.; Lees, Anthea C.; Chem. Commun. 2004, (7), 776-777, DOI: 10.1039/B315483A ; Solvent templated synthesis of metal-​organic frameworks: structural characterization and properties of the 3D network isomers {[Mn(dcbp)​]​·1​/2DMF}​n and {[Mn(dcbp)​]​·2H2O}​n
2) Tynan, Eithne; Jensen, Paul; Kelly, Niamh R.; Kruger, Paul E.; Lees, Anthea C.; Moubaraki, Boujemaa; Murray, Keith S.; Dal. Trans. 2004, (21), 3440-3447, DOI: 10.1039/B408961H ; The ligand, the metal and the Holey'-​host: Synthesis, structural and magnetic characterization of Co(II)​, Ni(II) and Mn(II) metal-​organic frameworks incorporating 4,​4'-​dicarboxy-​2,​2'-​bipyridine
3) Shi, Peng-Fei; Zhao, Bin; Xiong, Gang; Hou, Yin-Ling; Cheng, Peng; Chem. Commun. 2012, 48(66), 8231-8233, DOI: 10.1039/c2cc33707j ; Fast capture and separation of, and luminescent probe for, pollutant chromate using a multi-​functional cationic heterometal-​organic framework
4) Fang, Ming; Li, Ji-Jing; Shi, Peng-Fei; Zhao, Bin; Cheng, Peng;  Dal. Trans. 2013, 42(18), 6553-6563, DOI: 10.1039/c3dt32861a ; Structures, luminescence, and slow magnetic relaxation of eight 3D lanthanide-​organic frameworks
5) Li, Lina; Zhang, Shuquan; Xu, Liangjin; Han, Liang; Chen, Zhong-Ning; Luo, Junhua; Inorg. Chem. 2013, 52(21), 12323-12325, DOI: 10.1021/ic402158n ; An Intensely Luminescent Metal-​Organic Framework Based on a Highly Light-​Harvesting Dicyclo-​Metalated Iridium(III) Unit Showing Effective Detection of Explosives
HNMR-6813-38-3-CS013214.pdf Download
[2,2'-Bipyridine]-4,4'-dicarboxylic acid
[2,2'-Bipyridine]-4,4'-dicarboxylic acid

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