Product Name:1,3,5,7-tetrakis(4-formylphenyl)adamantaneSynonymous:TFPA;4,4',4'',4'''-Tricyclo[3.3.1.13,7]decane-1,3,5,7-tetrayltetrakis[benzaldehyde] CAS:645401-15-6
Basic Info
M.F. |
C38H32O4 |
M.W. |
552.65828 |
Appearance |
 |
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis
2) It can be used to synthesize (DCFS) [R1];
3) It can be used to synthesize polyaminal networks: Pan-1, pan-2 [R2];
4) It can be used to synthesize porus poly (Schiff base) s: psn-da, psn-tapb, psn-tapa, psn-tapm [R3]
Characterization
Reference
1) Duncan, Nathan C.; Hay, Benjamin P.; Hagaman, Edward W.; Custelcean, Radu; Tetrahedron 2012, 68(1), 53-64, DOI: 10.1016/j.tet.2011.10.052 ; Thermodynamic, kinetic, and structural factors in the synthesis of imine-linked dynamic covalent frameworks
2) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; Macromolecules 2014, 47(19), 6664-6670, DOI: 10.1021/ma501497c ; Tetraphenyladamantane-Based Polyaminals for Highly Efficient Captures of CO2 and Organic Vapors
3) Li, Guiyang; Zhang, Biao; Yan, Jun; Wang, Zhonggang; J. Mater. Chem. A 2014, 2(44), 18881-18888,DOI: 10.1039/C4TA04429K ; Micro- and mesoporous poly(Schiff-base)s constructed from different building blocks and their adsorption behaviors towards organic vapors and CO2 gas