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[1,1'-Biphenyl]-4,4'-diamine,3,3'-dinitro-
[1,1'-Biphenyl]-4,4'-diamine,3,3'-dinitro-
CAS:6271-79-0 M.F.:C12H10N4O4 M.W.:274.2322
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Product Name:3,3''-Dinitrobenzidine
Synonymous:3,​3'-​Dinitro-​1,​1'-​biphenyl-​4,​4'-​diamine
CAS:6271-79-0
Basic Info
M.F. C12H10N4O4 M.W. 274.2322
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:TpBD-(NO2)2 [r1]; Poly(benzimidazole amide imide) Copolymers [r4]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P.; Lukose, Binit; Kunjir, Shrikant M.; Chaudhary, Minakshi; Babarao, Ravichandar; Heine, Thomas; Banerjee, Rahul; Journal of the American Chemical Society 2013, 135(47), 17853-17861, DOI: 10.1021/ja408121p ; Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
2) Mann, John; Baron, Anne; Opoku-Boahen, Yaw; Johansson, Eric; Parkinson, Gary; Kelland, Lloyd R.; Neidle, Stephen; Journal of Medicinal Chemistry 2001, 44(2), 138-144, DOI: 10.1021/jm000297b ; A New Class of Symmetric Bisbenzimidazole-​Based DNA Minor Groove-​Binding Agents Showing Antitumor Activity
3) Lohse, Maria S.; Stassin, Timothee; Naudin, Guillaume; Wuttke, Stefan; Ameloot, Rob; De Vos, Dirk; Medina, Dana D.; Bein, Thomas; Chem. Mater. 2016, 28(2), 626-631, DOI: 10.1021/acs.chemmater.5b04388 ; Sequential Pore Wall Modification in a Covalent Organic Framework for Application in Lactic Acid Adsorption
4) Wang, Huei-Hsiung; Wu, Shu-Ping; J. Polym. Res. 2005, 12(1), 37-47, DOI: 10.1007/s10965-004-1307-y ; Synthesis and Their Thermal and Thermo-​Oxidative Properties of Poly(benzimidazole amide imide) Copolymers

5) Fernandes, Soraia P. S.; Kovar, Petr; Psenicka, Milan; Silva, Artur M. S.; Salonen, Laura M.; Espina, Begona; ACS Applied Mater.& Interfaces 2021, 13(13), 15053-15063, DOI: 10.1021/acsami.0c18808 ; Selection of covalent organic framework pore functionalities for differential adsorption of microcystin toxin analogues

[1,1'-Biphenyl]-4,4'-diamine,3,3'-dinitro-
[1,1'-Biphenyl]-4,4'-diamine,3,3'-dinitro-

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