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4,4'-Diamino-3,3',5,5'-tetrabromobiphenyl
4,4'-Diamino-3,3',5,5'-tetrabromobiphenyl
CAS:62477-23-0 M.F.:C12H8N2Br4 M.W.:499.82132
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Product Name:4,​4'-​Diamino-​3,​3',​5,​5'-​tetrabromobiphenyl
Synonymous:;3,​3',​5,​5'-​Tetrabromo[1,​1'-​biphenyl]​-​4,​4'-​diamine; 3,​5,​3',​5'-​Tetrabromo-​biphenyl-​4,​4'-​diamine
CAS:62477-23-0
Basic Info
M.F. C12H8N2Br4 M.W. 499.82132
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:MOF Linker Intermediate
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Wehrmann, Peter; Mecking, Stefan; Organometallics 2008, 27(7), 1399-1408, DOI: 10.1021/om700942z ; Highly active binuclear neutral nickel(II) catalysts affording high molecular weight polyethylene
2) Wen, Hui-Min; Li, Bin; Wang, Hailong; Krishna, Rajamani; Chen, Banglin; Chem. Commun. 2016, 52(6), 1166-1169, DOI: 10.1039/C5CC08210B ; High acetylene​/ethylene separation in a microporous zinc(II) metal-​organic framework with low binding energy
3) He, Hongming; Sun, Fuxing; Aguila, Briana; Perman, Jason A.; Ma, Shengqian; Zhu, Guangshan; J. Mater. Chem. A 2016, 4(39), 15240-15246, DOI: 10.1039/C6TA05098K ; A bifunctional metal-​organic framework featuring the combination of open metal sites and Lewis basic sites for selective gas adsorption and heterogeneous cascade catalysis
4) Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Liu, Caiping; Lollar, Christina; Wu, Mingyan; Yuan, Daqiang; Zhou, Hong-Cai; Hong, Maochun; J. Am. Chem. Soc. 2017, 139(46), 16939-16945, DOI: 10.1021/jacs.7b09973 ; Control the Structure of Zr-​Tetracarboxylate Frameworks through Steric Tuning
4,4'-Diamino-3,3',5,5'-tetrabromobiphenyl
4,4'-Diamino-3,3',5,5'-tetrabromobiphenyl

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