Home > Product Category > COFs Linkers > Aldehyde COF Linkers > 4d-Aldehyder COF Linkers
Add to Favorites
Tetrakis(4-formylphenyl)methane
Tetrakis(4-formylphenyl)methane
CAS:617706-61-3 M.F.:C29H20O4 M.W.:432.4667
Pricing //
Product Name:4-[tris(4-formylphenyl)methyl]benzaldehyde
Synonymous:TFPM; 4,​4',​4'',​4'''-​methanetetrakis-​benzaldehyde
CAS:617706-61-3
Basic Info
M.F.  C29H20O4 M.W.  432.4667
Appearance
Properties
1) 617706-61-3 Dissolved in DCM, DMF, DMSO, etc.
2) Sealed at 2-8 ℃
Appications
1) It could be used as monomer linker for COF synthesis:3D-COF [r2]; (benzimidazole-​linked polymer) BILP-1 [r3]; (Porous imine-​linked networks)PIN-2 [r4]; 3D-OH COF [r5]; 3D-​IL-​COFs [r6]
Characterization
HNMR
 
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Fournier, J.; Wang, X.; Wuest, J.; Canadian J. Chem. 2003, 81(5), 376-380, DOI:10.1139/V03-056 ; Derivatives of tetraphenylmethane and tetraphenylsilane: Synthesis of new tetrahedral building blocks for molecular construction 
2) X. Guan,  Y. Ma,  H. Li,   Y. Yusran,  M. Xue, Q. Fang,  Y. Yan, V. Valtchev, S. Qiu,  J. Am. Chem. Soc. 2018, 140, 4494– 4498, DOI:10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks 
3) Rabbani, M.; El-Kaderi, H.; Chem. Mater. 2011, 23(7), 1650-1653, DOI:10.1021/cm200411p
4) Popp, N.; Homburg, T.; Stock, N.; Senker, J.; J. Mater. Chem. A 2015, 3(36), 18492-18504, DOI:10.1039/C5TA02504D ; Porous imine-based networks with protonated imine linkages for carbon dioxide separation from mixtures with nitrogen and methane 
5) Lu, Q.; Ma, Y.; Li, H.; Guan, X.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Qiu, S.; Valtchev, Valentin.; Angew. Chem., Int. Ed. 2018, 57(21), 6042-6048, DOI: 10.1002/anie.201712246
6) Guan, X.; Ma, Y.; Li, H.; Yusran, Y.; Xue, M.; Fang, Q.; Yan, Y.; Valtchev, V.; Qiu, S.; J. Am. Chem. Soc. 2018, 140, 13, 4494-4498, DOI: 10.1021/jacs.8b01320 ; Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks 
HNMR-617706-61-3-CS013207.pdf Download
617706-61-3-CS014173.pdf Download
617706-61-3-CS014472.pdf Download
617706-61-3-CS017545.pdf Download
617706-61-3-CS017843.pdf Download
617706-61-3-CS018014.pdf Download
Tetrakis(4-formylphenyl)methane
Tetrakis(4-formylphenyl)methane

OK