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1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
CAS:60681-68-7 M.F.:C15H9N9 M.W.:315.292
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Product Name:1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
Synonymous:TPymT
CAS:60681-68-7
Basic Info
M.F.  C15H9N9 M.W.  315.292
Appearance  
Properties
1)  Soluble in water, slightly soluble in DMF, DMSO, etc
2)  Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: [Co(bpcam)2]ClO4·dmso·H2O [r3]; [Cd2(TPymT)​(SO4)​2(H2O)​6]​ [r4]; [Ag2(BPymTz)2] [r5]
Characterization
HNMR
MS
FTIR
NA
HPLC
NA
Reference
1) Case, Francis H.; Koft, Emil; Journal of the American Chemical Society 1959, 81, 905-906, DOI: 10.1021/ja01513a037 ;  The synthesis of certain substituted 1,​3,​5-​triazines containing the ferroin group
2) Lerner, E. I.; Lippard, S. J.; Journal of the American Chemical Society 1976, 98(17), 5397-5398, DOI: 10.1021/ja00433a061 ; 2,​4,​6-​Tris(2-​pyrimidyl)​- and 2,​4,​6-​tris(2-​pyridyl)​-​1,​3,​5-​triazines hydrolyze in the presence of copper(II) to form a novel bis(aryl)​carboximidato chelate complex
3) Garcia, Ana M.; Bassani, Dario M.; Lehn, Jean-Marie; Baum, Gerhard; Fenske, Dieter; Chemistry - A European Journal 1999, 5(4), 1234-1238, DOI: 10.1002/(SICI)1521-3765(19990401)5:4<1234::AID-CHEM1234>3.0.CO;2-G ;  Self-​assembly of multicomponent multimetallic lead(II) complexes of cylindrical architecture
4) Frost, Jamie M.; Kobera, Libor; Pialat, Amelie; Zhang, Yixin; Southern, Scott A.; Gabidullin, Bulat; Bryce, David L.; Murugesu, Muralee; Chem. Commun. 2016, 52(70), 10680-10683, DOI: 10.1039/C6CC04940K ; From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-​state NMR
5) Safin, Damir A.; Pialat, Amelie; Leitch, Alicea A.; Tumanov, Nikolay A.; Korobkov, Ilia; Filinchuk, Yaroslav; Brusso, Jaclyn L.; Murugesu, Muralee; Chem. Commun. 2015, 51(46), 9547-9550, DOI: 10.1039/C5CC01597A ; Anion-​induced AgI self-​assemblies with electron deficient aromatic ligands: anion-​π-​system interactions as a driving force for templated coordination networks
60681-68-7-CS017173.pdf Download
60681-68-7-CS017173-MS.pdf Download
1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-
1,3,5-Triazine, 2,4,6-tri-2-pyrimidinyl-

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