Product: COF-TMP-DFB
Synonyms: NKCOF-41 ; NK41 ; 1,4-Benzenedicarboxaldehyde, polymer with 2,4,6-trimethylpyridine;
CAS:57469-15-5
Basic Information
Unit MF. |
C8H11N.C8H6O2 |
Unit MW. |
255.31 |
Linkers |
Terephthalaldehyde( CAS:623-27-8 ); 2,4,6-Trimethylpyridine(CAS:108-75-8 ) |
Pore Size |
1.8 nm |
Pore volume |
0.99cm3/g |
Surface Area |
BET >900m2/g
|
Analog Structure |
  |
Product Property
Appearance |
Yellow powder |
 |
Particle Size |
irregular nanoparticle clusters |
Stability
1) COF-TMP-DFB has good chemical stability, acid and alkali resistance, a large number of pyridine sites, and semiconductor activity;
2) COF-TMP-DFB has high thermal stability
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 100 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas and pollutant adsorption
2) COF-TMP-DFBF has good pores that can be used to load other catalysts
3) COF-TMP-DFBF has greater electron delocalization that can be used in photocatalysis and energy storage
4) COF-TMP-DFBF has carbon carbon bonds, which can combine photoluminescence properties and stability, and can be used in fields such as biological imaging and chemical sensing
Characterizations
References
1) Zhang, Fan; Meng, Fancheng; Bi, Shuai; China, CN114409862 A 2022-04-29; Vinyl-bridged two-dimensional covalent organic framework material based on 2,4,6-trimethylpyridine and preparation method thereof; 一种基于2,4,6-三甲基吡啶的乙烯基桥联二维共价有机框架材料及其制备方法
2) Zhang, Penghui; Wang, Zhifang; Wang, Sa; Wang, Jian; Liu, Jinjin; Wang, Ting; Chen, Yao; Cheng, Peng; Zhang, Zhenjie; Angewandte Chemie, International Edition 2022 , 61(44), e202210447; DOI: 10.1002/anie.202213247; Fabricating Industry-Compatible Olefin-Linked COF Resins for Oxoanion Pollutant Scavenging