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IRMOF-3
IRMOF-3
CAS:473981-31-6 M.F.:C24H15N3O13Zn4 M.W.:814.95
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Product: IRMOF-3
Synonyms: NH2BDC-MOF-5
CAS:473981-31-6

Basic Information
Unit MF. C24H5N3O13Zn4 Unit MW. 804.8688
Coordination  Metal Zn Linkers 2-Amino Terephthalic Acid(CAS:10312-55-7)
Aperture 1.5  nm Pore volume  
Surface Area  BET >2000m2/g
Analog Structure  
Product Property
Appearance Light Organce Powder  
Particle Size irregular bulk particles
Stability
1) IRMOF-3 could be stable in air for weeks; instable in aqueous conditions
2)Thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for 3 hours at 100 degree in vacuum.
Other Features
Fluorescence: 460nm fluorescence excited by 340nm UV light
Applications
1) Gas and pollutant adsorption
2) Good drug carrier, which is able to decompose in stomach and release the drug content
3) Lewis acid catalyst for irganic reactions, e.g. Knoevenagel condensation
Characterizations
XRD
XRD-IRMOF-3
BET
BET-IRMOF-3
SEM
NA
FTIR
NA
References
1) M. Eddaoudi, J. Kim1, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295(5554), 469-472, DOI: 10.1126/science.1067208 ; Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
2) Wei, J.-Z., Wang, X.-L., Sun, X.-J., Dong, H., Zhang, F.-M., Inorg. Chem. 2018, 57, 3818-3824, DOI: 10.1021/acs.inorgchem.7b03174 ; Rapid and Large-Scale Synthesis of IRMOF-3 by Electrochemistry Method with Enhanced Fluorescence Detection Performance for TNP
IRMOF-3
IRMOF-3

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