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1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene
1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene
CAS:42837-44-5 M.F.:C27H21Br3 M.W.:585.16764
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Product Name:1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene
Synonymous:TBMPB;4,​4''-​Bis(bromomethyl)​-​5'-​[4-​(bromomethyl)​phenyl]​-​1,​1':3',​1''-​terphenyl
CAS:42837-44-5
Basic Info
M.F. C27H21Br3 M.W. 585.16764
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It can be used as an intermediate for the synthesis of MOF ligands
2) It can be used to synthesize hyperbranched polyphenylenes:[r2]
3) It can be used to synthesize rotaxane:[r4]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Voegtle, Fritz; Hohner, Gerd; Weber, Edwin; Chem. Commun. 1973, (11), 366-367, DOI: 10.1039/C39730000366 ; Novel multibridged macrocyclic systems
2) Kim, Young H.; Beckerbauer, Richard; Macromolecules (1994), 27(7), 1968-1971, DOI: 10.1021/ma00085a048 ; Role of End Groups on the Glass Transition of Hyperbranched Polyphenylene and Triphenylbenzene Derivatives
3) Zhang, Xue-Li; Guo, Cui-Ping; Yang, Qing-Yuan; Lu, Tong-Bu; Tong, Ye-Xiang; Su, Cheng-Yong; Chem. Mater. 2007, 19(19), 4630-4632, DOI: 10.1021/cm071767u ; Discrete Chiral Single-​Crystal Microtubes Assembled with Honeycomb Coordination Networks Showing Structural Diversity and Borromean Topology in One Single Crystal
4) Zhang, Ji-Na; Li, Hong; Zhou, Wei; Yu, Shi-Lin; Qu, Da-Hui; Tian, He; Chem.-Eur. J. 2013, 19(50), 17192-17200, DOI: 10.1002/chem.201303026 ; Fluorescence Modulation in Tribranched Switchable [4|Rotaxanes
1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene
1,​3,​5-​Tris[(4-​bromomethyl)​phenyl]​benzene

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