1,1 -Bis(2,4-dinitrophenyl)-4,4 -bipyridinium Dichloride
1,1 -Bis(2,4-dinitrophenyl)-4,4 -bipyridinium Dichloride
CAS:41168-79-0
M.F.:C22H16Cl2N6O8
M.W.:563.303842544556
Pricing
//
Product Name：N,N'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride
Synonymous：BDB;4,4'-Bipyridinium, 1,1'-bis(2,4-dinitrophenyl)-, dichloride; 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride;
CAS：41168-79-0
3) Sui, Qi; Ren, Xiang-Ting; Dai, Yu-Xiang; Wang, Kai; Li, Wen-Tao; Gong, Teng; Fang, Jia-Jia; Zou, Bo; Gao, En-Qing; Wang, Lin; Chem. Sci. 2017, 8(4), 2758-2768, DOI: 10.1039/C6SC04579K ; Piezochromism and hydrochromism through electron transfer: new stories for viologen materials
4) Liu, Jian-Jun; Guan, Ying-Fang; Lin, Mei-Jin; Huang, Chang-Cang; Dai, Wen-Xin; Cryst. Growth Des. 2015, 15(10), 5040-5046, DOI: 10.1021/acs.cgd.5b01026 ; Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the Detection of Organic Amines
Synonymous：BDB;4,4'-Bipyridinium, 1,1'-bis(2,4-dinitrophenyl)-, dichloride; 1,1'-Bis(2,4-dinitrophenyl)-4,4'-bipyridinium dichloride;
CAS：41168-79-0
Basic Info
| M.F. | C22N6O8+2.2[Cl-] | M.W. | 547.1768 | ||
| Appearance | |||||
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It can react with amino monomers to synthesize COF materials：BDB-TAPB-COGF [r2]
2) It can be used as a precursor for supramolecular ligands;
3) It can be used to synthesize vitamin based groups organic polymers [R5]
Characterization
Reference
1) Nanasawa, Masato; Miwa, Makio; Hirai, Michiko; Kuwabara, Tetsuo; J. Org. Chem. 2000, 65(2), 593-595,DOI: 10.1021/jo990911v ; Synthesis of viologens with extended π-conjugation and their photochromic behavior on near-IR absorption
2) Das, Gobinda; Skorjanc, Tina; Sharma, Sudhir Kumar; Gandara, Felipe; Lusi, Matteo; Shankar Rao, D. S.; Vimala, Sridurai; Krishna Prasad, Subbarao; Raya, Jesus; Han, Dong Suk; Jagannathan, Ramesh; Olsen, John-Carl; Trabolsi, Ali; Journal of the American Chemical Society 2017, 139(28), 9558-9565, DOI: 10.1021/jacs.7b02836 ; Viologen-Based Conjugated Covalent Organic Networks via Zincke Reaction5) Hua, Carol; Chan, Bun; Rawal, Aditya; Tuna, Floriana; Collison, David; Hook, James M.; D'Alessandro, Deanna M.; J. Mater. Chem. C 2016, 4(13), 2535-2544, DOI: 10.1039/C6TC00132G ; Redox tunable viologen-based porous organic polymers