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3,3',5,5'-Tetramethyl-1H,1'H-4,4'-bipyrazole
3,3',5,5'-Tetramethyl-1H,1'H-4,4'-bipyrazole
CAS:4054-67-5
M.F.:C10H14N4
M.W.:190.24496
Pricing
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Product Name：4,4′-Bi-3,5-dimethylpyrazole
Synonymous：H2mdpz; Me4bpz;
CAS：4054-67-5
Synonymous：H2mdpz; Me4bpz;
CAS：4054-67-5
Basic Info
| M.F. | C10H14N4 | M.W. | 190.24496 | ||
| Appearance |  |
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Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：e.g. MAF-X11[r6] ; SIFSIX-8 & SIFSIX-8-β [r7]
Characterization
Reference
1) Kruger, P.; Moubaraki, B.; Fallonb, G.; Murrayb, K.; J. Chem. Soc., Dalton Trans., 2000, 713-718, DOI: 10.1039/A908177A ; Tetranuclear copper(II) complexes incorporating short and long metal–metal separations: synthesis, structure and magnetism Tetranuclear copper(II) complexes incorporating short and long metal–metal separations: synthesis, structure and magnetism
2) Cuadro, A.; Elguero, J.; Navarro, P.; Chem. Pharm. Bull. 1985, 33(6), 2535-2540, DOI: 10.1248/cpb.33.2535 ; Binuclear Pyrazoles. I. Synthesis and Cytotoxic Activity of 1, 1'-Dibenzyl and 1, 1'-Dihydroxymethyl 4, 4'-Bispyrazoles. Binuclear pyrazoles. I. Synthesis and cytotoxic activity of 1,1'-dibenzyl and 1,1'-dihydroxymethyl 4,4'-bispyrazoles
3) Boldog, I.; Rusanov, E.; Chernega, A.; Sieler, J.; Domasevitch, K.; Polyhedron 2001, 20, 887-897, DOI: 10.1016/S0277-5387(01)00726-4 One- and two-dimensional coordination polymers of 3,3',5,5'-tetramethyl-4,4'-bipyrazolyl, a new perspective crystal engineering module
4) Hunger, J. Inorganica Chimica Acta 2013, 397, 60-68, DOI: 10.1016/j.ica.2012.11.019 Synthesis and structure of coordination polymers of Mn2+, Cu2+, Ag+, Zn2+ and Cd2+ by combination of bipyrazole and diphenate ligands
5) Zhang, E.; Jia, Q.; Zhang, J.; Ji, Z.; Chin. J. Chem. 2016, 34(2), 191-195, DOI: 10.1002/cjoc.201500640 Metal-Anion Coordination and Linker-Anion Hydrogen Bonding in the Construction of Metal-Organic Frameworks from Bipyrazole
6) Lin, Rui-Biao; Li, Fang; Liu, Si-Yang; Qi, Xiao-Lin; Zhang, Jie-Peng; Chen, Xiao-Ming; Angew. Chem., Int. Ed. 2013, 52(50), 13429-13433, DOI: 10.1002/anie.201307217 ; A Noble-Metal-Free Porous Coordination Framework with Exceptional Sensing Efficiency for Oxygen
7) SOUMYA MUKHERJEE , NIVEDITA SIKDAR, DANIEL O’NOLAN , DOUGLAS M. FRANZ, VICTORIA GASCÓN , AMRIT KUMAR , NAVEEN KUMAR , HAYLEY S. SCOTT, DAVID G. MADDEN , PAUL E. KRUGER , MICHAEL J. ZAWOROTKO, SCIENCE ADVANCES 2019, 5, 11, eaax 9197, DOI: 10.1126/sciadv.aax9171 ; Trace CO2 capture by an ultramicroporous physisorbent with low water affinity
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