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9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetramine
9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetramine
CAS:376356-61-5 M.F.:C25H20N4 M.W.:376.4531
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Product Name:9,​9'-​Spirobi[9H-​fluorene]​-​2,​2',​7,​7'-​tetramine
Synonymous:TASBF;2,2',7,7'-Tetraamino-9,9'-spirobifluorene
CAS:376356-61-5
Basic Info
M.F. C25H20N4 M.W. 376.4531
Appearance  
Properties
1)   It is soluble in DCM,DMF,DMSO,etc.
2)   Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:Porous Hydrogen-​Bonded Networks; azo-linked polymers ALP-5 [r3]; Spiro-PDI [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Fournier, J.; Maris, T.; Wuest, J.; J. Org. Chem. 2004, 69(6), 1762-1775, DOI: 10.1021/jo0348118 ; Molecular Tectonics. Porous Hydrogen-​Bonded Networks Built from Derivatives of 9,​9'-​Spirobifluorene
2) Weber, J.; Antonietti, M.; Thomas, A.; Macromolecules 2008, 41(8), 2880-2885, DOI:10.1021/ma702495r ; Microporous Networks of High-​Performance Polymers: Elastic Deformations and Gas Sorption Properties
3) Arab, P.; Parrish, E.; Islamoglu, T.; El-Kaderi, H.; J. Mater. Chem. A 2015, 3(41), 20586-20594DOI: 10.1039/C5TA04308 ; Synthesis and evaluation of porous azo-​linked polymers for carbon dioxide capture and separation
4) Du, Y.; Jiang, L.; Zhou, J.; Qi, G.; Li, X.; Yang, Y.; Org. Lett. 2012, 14(12), 3052-3055, DOI: 10.1021/ol300985h ; Perylenetetracarboxylic Diimide Derivatives Linked with Spirobifluorene
376356-61-5-CS014448.pdf Download
9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetramine
9,9'-Spirobi[9H-fluorene]-2,2',7,7'-tetramine

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