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1,4-bis(1,2,4-triazol-1-yl)butane
1,4-bis(1,2,4-triazol-1-yl)butane
CAS:345952-55-8 M.F.:C8H12N6 M.W.:192.22108
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Product Name:1,​4-​bis(1,​2,​4-​triazol-​1-​yl)​butane
Synonymous:btb;1,​1'-​(1,​4-​Butanediyl)​bis[1H-​1,​2,​4-​triazole]
CAS:345952-55-8
Basic Info
M.F. C8H12N6 M.W. 192.22108
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Cu6(btb)​3(P2W18O62)​]​·2H2O [r2]; [Co(H2abtc)​(4,​4'-​bipy)​0.5(H2O)​] [r4]; [Zn(mip)​(btb)​]​ [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Wang, Xin-Long; Qin, Chao; Wang, En-Bo; Su, Zhong-Min; Chem.- Eur. J. 2006, 12(10), 2680-2691, DOI: 10.1002/chem.200501242 ; Metal nuclearity modulated four-​, six-​, and eight-​connected entangled frameworks based on mono-​, bi-​, and trimetallic cores as nodes
2) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Han, Zhan-gang; Ma, Jian-fang; Su, Zhong-min; Hu, Ning-hai; Jia, Heng-qing; Inorg. Chem. 2008, 47(8), 3274-3283, DOI: 10.1021/ic7023082 ; Assembly of the Highest Connectivity Wells-​Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
3) Tian, Ai-xiang; Ying, Jun; Peng, Jun; Sha, Jing-quan; Pang, Hai-jun; Zhang, Peng-peng; Chen, Yuan; Zhu, Min; Su, Zhong-min; Inorg. Chem. 2009, 48(1), 100-110, DOI: 10.1021/ic801338b ; Assemblies of Copper Bis(triazole) Coordination Polymers Using the Same Keggin Polyoxometalate Template
4) Zhao, Jun; Li, Dong-Sheng; Ke, Xi-Jun; Liu, Bin; Zou, Kun; Hu, Huai-Ming; Dalton Trans. 2012, 41(9), 2560-2563, DOI: 10.1039/c2dt12170k ; Auxiliary ligand-​directed structural variation from 2D→3D polythreaded net to 3-​fold interpenetrating 3D pillar-​layered framework: Syntheses, crystal structures and magnetic properties

5) Han, Min-Le; Chang, Xin-Hong; Feng, Xun; Ma, Lu-Fang; Wang, Li-Ya; CrystEngComm 2014, 16(9), 1687-1695, DOI: 10.1039/c3ce41968a ; Temperature and pH driven self-​assembly of Zn(II) coordination polymers: crystal structures, supramolecular isomerism, and photoluminescence

1,4-bis(1,2,4-triazol-1-yl)butane
1,4-bis(1,2,4-triazol-1-yl)butane

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