CAS 338451-18-6|pbbimb|CHEMSOON-MOF/COFmaterial professional supplier

Product Name：1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-benzimidazole]
Synonymous：pbbimb;1,4-Bis(benzimidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
CAS：338451-18-6

Basic Info

M.F.	C26H26N4		M.W.	394.51144
Appearance

Properties

1) It is soluble in DMF and DMSO
2) Sealed at room temperature

Appications

1) It could be used as monomer linker for MOF synthesis:[Ag2(pbbimb)3] [r1]

Characterization

HNMR

FTIR

HPLC

Reference

1) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Zhang, Hua-Xin; Kang, Bei-Sheng; J. Chem. Soc., Dalton Trans. 2001, (4), 359-361, DOI: 10.1039/b010118o ; Coordination-directed assembly of trigonal and tetragonal molecular boxes encapsulating anionic guests

2) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Kang, Bei-Sheng; Inorg. Chem. 2001, 40(10), 2210-2211, DOI: 10.1021/ic0014282 ; Unusual Noninterpenetrating (3,6) Topological Network Assembled by Semirigid Benzimidazole-Based Bridging Ligand

3) Su, Cheng-Yong; Cai, Yue-Peng; Chen, Chun-Long; Smith, Mark D.; Kaim, Wolfgang; Zur Loye, Hans-Conrad; Journal of the American Chemical Society 2003, 125(28), 8595-8613, DOI: 10.1021/ja034267k ; Ligand-Directed Molecular Architectures: Self-Assembly of Two-Dimensional Rectangular Metallacycles and Three-Dimensional Trigonal or Tetragonal Prisms

4) Zhang, Qian; Zhang, Jianyong; Yu, Qiong-Yan; Pan, Mei; Su, Cheng-Yong; Cryst. Growth & Des. 2010, 10(9), 4076-4084, DOI: 10.1021/cg100742c ; Ring-Opening Isomerization Based on the 3-Connecting Node: Formation of a 0-D M2L3 Cage, 1-D Loop-and-Chain, and 2-D (6, 3) Network

5) Liu, Qing-Xiang; Hu, Ze-Liang; Yu, Shao-Cong; Zhao, Zhi-Xiang; Wei, Deng-Che; Li, Hui-Long; ACS Omega 2018, 3(4), 4035-4047, DOI: 10.1021/acsomega.8b00205 ; NHC Pd(II) and Ag(I) Complexes: Synthesis, Structure, and Catalytic Activity in Three Types of C-C Coupling Reactions