Manganese, [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)-κN1,κN1′]-, dihydrate
Manganese, [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)-κN1,κN1′]-, dihydrate
CAS:332405-32-0
M.F.:C12H6MnN2O4.2H2O
M.W.:333.16
Pricing
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Product: Mn-bpdc
Synonyms: Manganese, [[2,2′-bipyridine]-4,4′-dicarboxylato(2-)-κN1,κN1′]-, dihydrate
CAS：332405-32-0
Basic Information
| Unit MF. | C12H6MnN2O4.2H2O | Unit MW. | 333.16 | ||
| Coordination Metal | Mn | Linkers |
2,2'-bipyridine-4,4'-dicarboxylic acid (H2BPDC) (CAS: 120-73-6) |
||
| Pore Size | 4.2 Å × 6.1 Å | Pore Volume | 0.10 cm3/g | ||
| Surface Area | 159 m2/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | White Crystals | |||
| Particle Size | Lamellar microstructures | |||
Stability
1) Mn-bpdc remains structurally intact after soaking in water at room temperature for 60 days, in air for 60 days, and in boiling water (100°C) for 24 hours.
2) Thermal decomposition begins at 480°C.
2) Thermal decomposition begins at 480°C.
Preservation
1) Keep in dry and cool conditions.
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use.
Other Features
Fluorescence: NA
Applications
1) Efficient separation of 1,3-butadiene from other C4 hydrocarbons such as n-butene, iso-butene, n-butane, and iso-butane.
2) Dynamic separation of C4 hydrocarbons in industrial applications.
Characterizations
References
1) Lu Wang, Hongliang Huang, Hejin Zhu, Yanjiao Chang, Xiangyu Guo, Fan Yang, Chongli Zhong; AIChE J. 2022, 68(4), e17568, DOI: 10.1002/aic.17568 ; Efficient separation of 1,3-butadiene from C4 hydrocarbons by flexible metal–organic framework with gate-opening effect