Product: Py-BSZ-COF
Synonyms: NA
CAS:2929303-06-8
Basic Information
Unit MF. |
C44H26O4.C22H14N4S |
Unit MW. |
985.12 |
Coordination Metal |
None |
Linkers |
1,3,6,8-tetrakis(4-formylphenyl)pyrene (CAS: 1415238-25-3)
4,4′-(benzothiadiazole-4,7-diyl)diacetonitrile (CAS:2512845-03-1 )
|
Pore Size |
~2.1 nm |
Pore Volume |
Not specified |
Surface Area |
688 m²/g |
Analog Structure |
/ |
Product Property
Appearance |
|
|
Particle Size |
Irregular bulk particles |
Stability
1) it can be inferred that Py-BSZ-COF has certain stability in organic solvents as it can be synthesized in them.
2) it shows high stability in thermogravimetric analysis.
Preservation
1) Keep in dry and cool conditions
2) It is recommended to activate by heating in a vacuum oven at room temperature for 3 hours before use.
Other Features
Fluorescence: NA
Applications
1) Photocatalysis: Py-BSZ-COF shows good catalytic performance in the photocatalytic asymmetric α-alkylation of aldehydes, which can be used to synthesize chiral amine compounds.
2) Gas adsorption: Due to its high specific surface area and porosity, it can be used in gas adsorption fields, such as the adsorption of carbon dioxide, hydrogen, etc.
Characterizations
References
1) Zhou, Zimo; Li, Li; Dai, Lu; Liu, Huanyu; Li, Yueting; Li, Pengfei; Journal of Polymer Science, 2024, 62(8), 1621-1628, DOI: 10.1002/pol.20230164; The synthesis of highly crystalline covalent organic frameworks via the monomer crystal induction for the photocatalytic asymmetric α-alkylation of aldehydes