PI-COF-1
PI-COF-1
CAS:286831-92-3
M.F.:
M.W.:
Pricing
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Product: PICOF-1
Synonyms: Pyromellitic dianhydride-tris(4-aminophenyl)amine copolymer ; 1,4-Benzenediamine, N,N-bis(4-aminophenyl)-, polymer with 1H,3H-benzo[1,2-c:4,5-c']difuran-1,3,5,7-tetrone
CAS： 286831-92-3
Basic Information
| Unit MF. | (C18 H18 N4.C10 H2 O6)x | Unit MW. | 508.48 | ||
| Linkers | Tris(4-aminophenyl)amine（CAS: 5981-09-9）; Pyromellitic dianhydride (CAS: 89-32-7) | ||||
| Pore Size | 3.3 nm | Pore volume | 0.53 cm3 /g | ||
| Surface Area | BET > 800m2/g |
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| Analog Structure |  |
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Product Property
| Appearance | Black / Dark Brown Powders | |||
| Particle Size | irregular nanoparticle clusters | |||
Stability
1) PICOF-1 is stable in sealed condition for weeks, and stable in water and common organic solvent
2) Thermally stable, thermal decomposition temperature of PICOF-1 is above 450 ° C
2) Thermally stable, thermal decomposition temperature of PICOF-1 is above 450 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 12 hours at 80-100 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas and pollutant adsorption
2) With stable channel of 3.3nm, COF-v is a potential carrier of catalyst and prospective in enzyme encapsulation
2) With stable channel of 3.3nm, COF-v is a potential carrier of catalyst and prospective in enzyme encapsulation
Characterizations
References
1) Fang, Qianrong; Zhuang, Zhongbin; Gu, Shuang; Kaspar, Robert B.; Zheng, Jie; Wang, Junhua; Qiu, Shilun; Yan, Yushan; Nat. Commun. 2014, 5, 4503, DOI: 10.1038/ncomms5503 ; Designed synthesis of large-pore crystalline polyimide covalent organic frameworks;
2) Peiyu Zhao+, Yanhua Zhang+, Baoyu Sun, Rui Qiao, Chao Li, Pengqi Hai, Yingche Wang, Feng Liu, and Jiangxuan Song*; Angew. Chem. Int. Ed. 2024, e202317016; DOI：10.1002/anie.202317016; Enhancing Anion-Selective Catalysis for Stable Lithium Metal Pouch Cells through Charge Separated COF Interlayer【文献解读】