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Benzaldehyde, 4,4′-(2,1,3-benzothiadiazole-4,7-diyl)bis-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
Benzaldehyde, 4,4′-(2,1,3-benzothiadiazole-4,7-diyl)bis-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
CAS:2843634-50-2
M.F.:C21H18N6.C20H12N2O2S
M.W.:698.80
Pricing
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Product: BTDA-TAPT
Synonyms: Benzaldehyde, 4,4′-(2,1,3-benzothiadiazole-4,7-diyl)bis-, polymer with 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[benzenamine]
CAS: 2843634-50-2
Basic Information
| Unit MF. | C21H18N6.C20H12N2O2S | Unit MW. | 698.80 | ||
| Coordination Metal | None | Linkers |
1) 4,4'-(2,1,3-Benzothiadiazole-4,7-diyl)bis[benzaldehyde]（CAS:914651-17-5）; 2) (1,3,5-tris-(4-aminophenyl)triazine(CAS:14544-47-9) |
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| Pore Size | ~1.27 nm | Pore Volume | 0.68 cm³/g | ||
| Surface Area | 158.6 m²/g | ||||
| Analog Structure | Not Available | ||||
Product Property
| Appearance | Yellow powders, regular nanorod structures | |||
| Particle Size | 5~0-100 nm | |||
Stability
1) Stable in DMF and THF, but partially decomposes in 1 M NaOH and 1 M HCl.
2) Thermal decomposition temperature > 500°C.
2) Thermal decomposition temperature > 500°C.
Preservation
1) Store in a dry and cool condition.
2) No special activation required before use.
Other Features
No significant fluorescence.
Applications
1) Visible light-driven oxidative coupling of amines.
2) Heterogeneous photocatalysis for organic synthesis.
3) Efficient metal-free photocatalyst.
2) Heterogeneous photocatalysis for organic synthesis.
3) Efficient metal-free photocatalyst.
Characterizations
References
1) Qing Li, Juan Wang, Yize Zhang, Luis Ricardez-Sandoval, Guoyi Bai, Xingwang Lan; ACS Applied Materials & Interfaces 2021, 13, 39291−39303, DOI: 10.1021/acsami.1c08951; Structural and Morphological Engineering of Benzothiadiazole-Based Covalent Organic Frameworks for Visible Light-Driven Oxidative Coupling of Amines